磷酸金属盐类成核剂调控制备高流动抗冲共聚聚丙烯的研究

苟荣恒, 王勇, 刘义, 郭晓东, 韩李旺, 杨廷杰, 程敏

现代化工 ›› 2022, Vol. 42 ›› Issue (11) : 170 -173,178.

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现代化工 ›› 2022, Vol. 42 ›› Issue (11) : 170-173,178. DOI: 10.16606/j.cnki.issn0253-4320.2022.11.031
科研与开发

磷酸金属盐类成核剂调控制备高流动抗冲共聚聚丙烯的研究

    苟荣恒, 王勇, 刘义, 郭晓东, 韩李旺, 杨廷杰, 程敏
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Preparation of high-flow impact polypropylene in presence of metal phosphates nucleating agents

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摘要

考察了金属盐类成核剂TD-531和NA-11对煤基高流动抗冲聚丙烯K7760H的结晶性能、力学性能及熔融指数等的影响。结果表明,成核剂NA-11和TD-531的引入均可以有效促进K7760H的结晶过程,且低浓度下成核效果更加明显;添加250 μg/g成核剂TD-531和NA-11时,成核聚丙烯体系的结晶温度分别从空白聚丙烯的121.6℃提升至129.8℃和125.3℃。2种成核剂均可有效改善聚丙烯K7760H的拉伸强度且提升效果相当,而TD-531对弯曲模量的提升效果明显优于NA-11;但2种成核剂均使聚丙烯的冲击强度略有下降。添加成核剂使聚丙烯K7760H的熔融指数略有提高,表明成核剂对聚丙烯的流动性有一定提升作用。

Abstract

The effects of metal salt nucleating agents TD-531 and NA-11 on the crystallization performance,mechanical properties and melt index of coal-based high-flow impact polypropylene K7760H are studied.The results show that the addition of both NA-11 and TD-531 can effectively promote the crystallization process of K7760H,and the nucleation effect is more obvious at low concentration.The crystallization temperature of the nucleated polypropylene system increases from 121.6℃ of pure polypropylene to 129.8℃ and 125.3℃,respectively when 250 μg·g-1 of TD-531 and 250 μg·g-1 of NA-11 is added.Both NA-11 and TD-531 can effectively improve the tensile strength of polypropylene K7760H,while the improvement effect by TD-531 in flexural modulus is significantly better than that by NA-11.Both NA-11 and TD-531 can make the impact strength of polypropylene reduce slightly.Finally,the addition of nucleating agent slightly increases the melt index of polypropylene K7760H,indicating that the nucleating agent has a certain effect on improving the fluidity of polypropylene.

关键词

磷酸金属盐类成核剂 / 高流动 / 抗冲聚丙烯

Key words

metal phosphates-type nucleating agent / high flow / impact polypropylene

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磷酸金属盐类成核剂调控制备高流动抗冲共聚聚丙烯的研究[J]. 现代化工, 2022, 42(11): 170-173,178 DOI:10.16606/j.cnki.issn0253-4320.2022.11.031

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