PDF (5370K)
摘要
采用绿色工艺制备石墨烯(GR),以聚多巴胺(PDA)为黏合剂、混合纤维素滤膜(MCE)为基体,借助真空辅助抽滤法制备二氧化钛/石墨烯/多巴胺复合膜(TP-G/MCE)。研究了不同质量分数GR的TP-G的性能,考察了丙酮熏蒸透明化膜的柔韧性及对负载牢固度的影响等。结果表明,经丙酮蒸气渗透后,白色多孔的MCE膜变成透明TP-G膜,具有优异的柔韧性与负载牢固性。与TiO2相比,TP-G发生了明显红移,TP-8.0% G膜的光催化降解甲基橙的降解率为81.84%,经过3次光催化降解循环后降解率为80%。
Abstract
Graphene (GR) is prepared via a clean process, and titanium dioxide/graphene/dopamine composite membrane (TP-G/MCE) are prepared through vacuum-assisted filtration by using polydopamine (PDA) as binder and mixed cellulose filter membrane (MCE) as the substrate.The properties of TP-G membranes with different GR fractions are investigated, such as the flexibility of acetone fumigated transparent membranes (TP-G) and the effect on the loading firmness.It is shown that after being fumigated by acetone vapor, the white and porous MCE membranes change into transparent TP-G film, with excellent flexibility and load solidity.Compared with TiO2, TP-G has a significant red shift.The photocatalytic degradation rate of methyl orange by TP-8.0%G film is 81.84%, which is 80% after the film has been used for three cycles, presenting good degradation efficiency and repeatability.
关键词
剥离石墨烯
/
透明薄膜
/
光催化
/
二氧化钛-石墨烯-多巴胺薄膜
Key words
exfoliated graphene
/
transparent film
/
photocatalysis
/
titanium dioxide/graphene/dopamine membrane
Author summay
侯笑笑(1996-),女,硕士研究生,研究方向为光催化技术、光催化降解VOCs,380440859@qq.com
新型光催化复合膜TiO2/GR/PDA的制备及性能研究[J].
现代化工, 2022, 42(2): 188-192 DOI:10.16606/j.cnki.issn0253-4320.2022.02.038