煤直接液化残渣中易致癌致畸多环芳烃类化合物的分离分析

杨莹杰, 李鹏

现代化工 ›› 2021, Vol. 41 ›› Issue (S1) : 352 -354.

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现代化工 ›› 2021, Vol. 41 ›› Issue (S1) : 352-354. DOI: 10.16606/j.cnki.issn0253-4320.2021.S.074
分析测试

煤直接液化残渣中易致癌致畸多环芳烃类化合物的分离分析

    杨莹杰, 李鹏
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Separation and analysis of polycyclic aromatic hydrocarbons in direct coal liquefaction residues

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摘要

煤液化残渣是煤炭清洁转化的副产物,其成分中含有多种芳香类化合物以及杂原子化合物。利用溶剂萃取技术,结合气相色谱、质谱分析,对煤液化残渣中的多环芳烃的种类与分布进行研究。结果表明,煤液化残渣正己烷萃取物中检测到18种芳香族化合物,其中7,12-二甲基苯并[a]蒽、苯并[a]芘、茚并[1,2,3-c,d]芘、苯并[ghi]苝等具有强致癌致畸性。

Abstract

Coal liquefaction residue is a byproduct from clean conversation of coal, consisting of various polycyclic aromatic hydrocarbons and heteroatom-containing compounds.Solvent extraction technology combining with gas chromatography/mass spectrometry is applied to investigate the species and distribution of polycyclic aromatic hydrocarbons in coal liquefaction residue.It is indicated that 18 kinds of aromatic compounds are identified in the n-hexane extracts from coal liquefaction residue, among which 7, 12-dimethylbenzo[a]anthracene, benzo[a]pyrene, indeno[1, 2, 3-c, d]pyrene, benzo[ghi]perylene are of high carcinogenicity and teratogenicity.

关键词

煤液化残渣 / 致癌致畸 / 多环芳烃 / 溶剂萃取

Key words

coal liquefaction residues / carcinogenicity and teratogenicity / polycyclic aromatic hydrocarbons / solvent extraction

Author summay

杨莹杰(2000-),女,本科生,研究方向为煤液化残渣的分离分析,541327911@qq.com

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煤直接液化残渣中易致癌致畸多环芳烃类化合物的分离分析[J]. 现代化工, 2021, 41(S1): 352-354 DOI:10.16606/j.cnki.issn0253-4320.2021.S.074

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