NiTe/Ni@CC//AC/CC全固态柔性超级电容器的性能研究

钱豪, 刘湉湉, 聂仲武, 陈曙光

现代化工 ›› 2021, Vol. 41 ›› Issue (7) : 108 -112,117.

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现代化工 ›› 2021, Vol. 41 ›› Issue (7) : 108-112,117. DOI: 10.16606/j.cnki.issn0253-4320.2021.07.023
科研与开发

NiTe/Ni@CC//AC/CC全固态柔性超级电容器的性能研究

    钱豪, 刘湉湉, 聂仲武, 陈曙光
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Study on performance of NiTe/Ni@CC//AC/CC all-solid-state flexible supercapacitor

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摘要

采用电镀和水热反应两步法制备了一种高柔性NiTe/Ni@CC超级电容器正极材料。利用X射线衍射、扫描电镜、能谱仪和电化学工作站对NiTe/Ni@CC电极进行了表征与分析。结果表明,该电极具有CC-Ni-NiTe的层次结构;在电流密度为 5 mA/cm2时,电极的面积比电容达到2.85 F/cm2;由该电极组装的NiTe/Ni@CC//AC/CC全固态柔性超级电容器在 5.57 mW/cm2的面功率密度下可提供高达0.50 mW·h/cm2的面能量密度,并且在0~90°的2 000次弯曲循环后,具有77.20%的初始电容保持率。

Abstract

A highly flexible NiTe/Ni@CC electrode material for supercapacitor is fabricated via a two-step approach including electroplating and in situ growth.X-ray diffraction (XRD),scanning electron microscopy (SEM),energy dispersive spectroscopy (EDS) and electrochemical workstation are employed for the characterization and analysis of NiTe/Ni@CC electrode material.It is shown that the electrode material has a CC-Ni-NiTe hierarchical structure.As the current density is 5 mA·cm-2,the areal specific capacitance of the electrode reaches 2.85 F·cm-2.NiTe/Ni@CC//AC/CC all-solid-state flexible supercapacitor assembled by this electrode can provide an area energy density as high as 0.50 mWh·cm-2 at an area power density of 5.57 mW·cm-2,and has a capacitance retention rate of 77.20% after 2,000 bending cycles from 0° to 90°.

关键词

电镀 / 层次结构 / 柔性 / 超级电容器 / 水热反应

Key words

electroplating / hierarchical structure / flexible / supercapacitor / hydrothermal reaction

Author summay

钱豪(1996-),男,硕士研究生,研究方向为超级电容器,1104533817@qq.com

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NiTe/Ni@CC//AC/CC全固态柔性超级电容器的性能研究[J]. 现代化工, 2021, 41(7): 108-112,117 DOI:10.16606/j.cnki.issn0253-4320.2021.07.023

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