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摘要
为实现柴油产品质量升级,选择抚顺石油化工研究院研制的新一代加氢精制催化剂FF-66替换原加氢精制催化剂FF-36,与加氢裂化催化剂FC-20组合使用生产国Ⅵ低凝柴油。结果表明,采用FF-66/FC-20组合催化剂处理催化柴油、焦化汽油和直馏柴油组成的混合原料(平均硫含量为2 742 μg/g),标定工况下的柴油产品硫含量降低至4.5 μg/g,氮含量降低至0.35 μg/g,多环芳烃质量分数降低至3.3%,十六烷值提高了3.5个单位,凝点降至-24℃。说明FF-66/FC-20催化剂活性匹配良好,具有优异的脱硫、脱氮性能和十六烷值增值能力,能够满足柴油加氢改质异构降凝装置生产国Ⅵ低凝柴油的需求。
Abstract
In order to upgrade the quality of diesel products,FF-66,a new generation hydrofining catalyst developed by Fushun Research Institute of Petroleum and Petrochemicals,is selected to replace previous FF-36 hydrofining catalyst,and is used jointly with hydrocracking catalyst FC-20 to produce low pour point diesel oil meeting China's national Ⅵ standard.Results show when the mixing feedstocks composing of catalytic diesel oil,coking gasoline and straight run diesel oil,with an average sulfur content of 2,742 μg·g-1,is treated by FF-66/FC-20 composite catalyst under calibration conditions,the sulfur content of diesel product drops to 4.5 μg·g-1,the nitrogen content drops to 0.35 μg·g-1,polycyclic aromatic hydrocarbon content drops to 3.3%,the cetane number increases by 3.5 units,and the condensation point decreases to -25℃.It is indicated that FF-66/FC-20 catalyst has good activity matching,excellent desulfurization and denitrification performance and cetane value-added ability,over which low pour point diesel meeting China's national Ⅵ standard can be produced in diesel hydrotreating and upgrading isomerization pour point reduction unit.
关键词
预硫化
/
联合应用
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低凝柴油
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国Ⅵ标准
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FC-20
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FF-66
Key words
pre-vulcanized
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combined application
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low pour point diesel
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China's national Ⅵ standard
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FC-20
/
FF-66
预硫化型FF-66/FC-20催化剂组合应用生产国Ⅵ低凝柴油[J].
现代化工, 2021, 41(5): 226-229 DOI:10.16606/j.cnki.issn0253-4320.2021.05.046