加氢裂化尾油异构脱蜡-补充精制产品探索研究

许海龙, 徐岩峰, 张翠侦, 宋君辉

现代化工 ›› 2021, Vol. 41 ›› Issue (5) : 208 -211,216.

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现代化工 ›› 2021, Vol. 41 ›› Issue (5) : 208-211,216. DOI: 10.16606/j.cnki.issn0253-4320.2021.05.042
工业技术

加氢裂化尾油异构脱蜡-补充精制产品探索研究

    许海龙, 徐岩峰, 张翠侦, 宋君辉
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Exploration research on products by isomeric dewaxing-supplementary refining of hydrocracking tail oil

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摘要

以中海油某炼厂加氢裂化装置尾油为原料,采用该炼厂石蜡基润滑油加氢装置异构脱蜡-补充精制段反应器现用催化剂,进行异构脱蜡-补充精制试验,考察了不同反应温度下生产高档润滑油基础油、化妆品级白油、食品级白油的可行性。结果表明,不同反应温度下均无法制备出高黏度指数(>100)且倾点合格的润滑油基础油;在反应压力15 MPa、空速1.0 h-1、氢油体积比800:1、异构脱蜡和补充精制段反应温度分别为330、240℃条件下,加氢生成油300~380℃馏分段(收率18.48%)和>380℃馏分段(收率36.79%)分别可以达到食品级白油(GB 1886.215—2016)、化妆品级白油(NB/SH 0007—2015)产品指标要求。

Abstract

Taking hydrocracking tail oil from a refinery of CNOOC as raw material,isomerization dewaxing and supplementary refining test are performed over the catalyst in service to investigate the feasibility of producing high-grade lubricating base oil,cosmetic-grade white oil and food-grade white oil at different reaction temperatures.The results show that the base oil with high viscosity index (>100) and qualified pour point cannot be prepared at any reaction temperatures.The distillate at 300-380℃ (a yield of 18.48%) and the distillate exceeding 380℃ (a yield of 36.79%) can respectively meet the product index requirements of food-grade white oil (GB 1886.215—2016) and cosmetics-grade white oil (NB/SH 0007—2015) when reaction pressure is 15 MPa,space velocity is 1.0 h-1,the ratio hydrogen to oil is 800:1 and the temperatures of isomerization dewaxing and supplementary refining sections are 330℃ and 240℃,respectively.

关键词

加氢裂化尾油 / 化妆品级白油 / 食品级白油 / 补充精制 / 异构脱蜡

Key words

hydrocracking tail oil / cosmetic-grade white oil / food-grade white oil / supplementary refining / isomerization dewaxing

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加氢裂化尾油异构脱蜡-补充精制产品探索研究[J]. 现代化工, 2021, 41(5): 208-211,216 DOI:10.16606/j.cnki.issn0253-4320.2021.05.042

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