PDF (1886K)
摘要
以中海油某炼厂加氢裂化装置尾油为原料,采用该炼厂石蜡基润滑油加氢装置异构脱蜡-补充精制段反应器现用催化剂,进行异构脱蜡-补充精制试验,考察了不同反应温度下生产高档润滑油基础油、化妆品级白油、食品级白油的可行性。结果表明,不同反应温度下均无法制备出高黏度指数(>100)且倾点合格的润滑油基础油;在反应压力15 MPa、空速1.0 h-1、氢油体积比800:1、异构脱蜡和补充精制段反应温度分别为330、240℃条件下,加氢生成油300~380℃馏分段(收率18.48%)和>380℃馏分段(收率36.79%)分别可以达到食品级白油(GB 1886.215—2016)、化妆品级白油(NB/SH 0007—2015)产品指标要求。
Abstract
Taking hydrocracking tail oil from a refinery of CNOOC as raw material,isomerization dewaxing and supplementary refining test are performed over the catalyst in service to investigate the feasibility of producing high-grade lubricating base oil,cosmetic-grade white oil and food-grade white oil at different reaction temperatures.The results show that the base oil with high viscosity index (>100) and qualified pour point cannot be prepared at any reaction temperatures.The distillate at 300-380℃ (a yield of 18.48%) and the distillate exceeding 380℃ (a yield of 36.79%) can respectively meet the product index requirements of food-grade white oil (GB 1886.215—2016) and cosmetics-grade white oil (NB/SH 0007—2015) when reaction pressure is 15 MPa,space velocity is 1.0 h-1,the ratio hydrogen to oil is 800:1 and the temperatures of isomerization dewaxing and supplementary refining sections are 330℃ and 240℃,respectively.
关键词
加氢裂化尾油
/
化妆品级白油
/
食品级白油
/
补充精制
/
异构脱蜡
Key words
hydrocracking tail oil
/
cosmetic-grade white oil
/
food-grade white oil
/
supplementary refining
/
isomerization dewaxing
加氢裂化尾油异构脱蜡-补充精制产品探索研究[J].
现代化工, 2021, 41(5): 208-211,216 DOI:10.16606/j.cnki.issn0253-4320.2021.05.042