NH3-SCR脱硝催化剂研究进展

戴豪波, 杜凯敏, 郑渭建, 刘春红, 胡晨晖, 卓佐西, 蒋楠

现代化工 ›› 2021, Vol. 41 ›› Issue (5) : 40 -44,48.

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现代化工 ›› 2021, Vol. 41 ›› Issue (5) : 40-44,48. DOI: 10.16606/j.cnki.issn0253-4320.2021.05.009
技术进展

NH3-SCR脱硝催化剂研究进展

    戴豪波, 杜凯敏, 郑渭建, 刘春红, 胡晨晖, 卓佐西, 蒋楠
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Research progress on NH3-SCR catalysts

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摘要

综述了NH3-SCR脱硝催化反应机理及近年来文献报道的脱硝催化剂体系(V、Mn、Ce基等过渡金属氧化物和复合氧化物催化剂,Fe、Cu离子交换型分子筛催化剂),并对各种催化剂的优势和不足进行分析评述。虽然目前催化剂体系众多,但催化剂宽裕的高活性操作温窗、高温水热稳定性和耐毒性仍有待提高。最后指出,开发新型催化剂、改善催化剂的高温水热稳定性、提升抗中毒能力和绿色合成是未来NH3-SCR脱硝催化剂研究的重要方向。

Abstract

The reaction mechanism of NH3-SCR is reviewed,and the recently reported catalyst systems are introduced,such as V-,Mn-,Ce-based transition metal oxide or composite oxide catalysts,Fe-zeolite catalysts and Cu-zeolite catalysts.The advantages and drawbacks of various kinds of catalysts are analyzed.Although there are many kinds of catalyst systems developed for NH3-SCR,some performances of the catalysts like wide operating temperature window,great hydrothermal stability and outstanding resistance to poisoning need to be improved.In the future,it is suggested for NH3-SCR to develop new types of catalysts,improve hydrothermal stability of the catalysts at high temperature,enhance catalysts' resistance to poisoning and develop "green" synthesis process.

关键词

氮氧化物 / 稳定性 / 活性 / 催化剂 / 选择催化还原 / 氨气

Key words

NOx / stability / activity / catalyst / SCR / NH3

Author summay

戴豪波(1972-),男,硕士,高级工程师,研究方向为能源环保,daihaobo@126.com

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NH3-SCR脱硝催化剂研究进展[J]. , 2021, 41(5): 40-44,48 DOI:10.16606/j.cnki.issn0253-4320.2021.05.009

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