磁性生物炭材料在含油废水处理中的应用研究

刘梅, 薛代惠美, 郭玉超, 刘新月, 朱鹏飞, 杨梅

现代化工 ›› 2021, Vol. 41 ›› Issue (3) : 149 -153.

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现代化工 ›› 2021, Vol. 41 ›› Issue (3) : 149-153. DOI: 10.16606/j.cnki.issn0253-4320.2021.03.030
科研与开发

磁性生物炭材料在含油废水处理中的应用研究

    刘梅, 薛代惠美, 郭玉超, 刘新月, 朱鹏飞, 杨梅
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Study on application of magnetic biochar in treatment of oil-bearing wastewater

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摘要

以天然废弃物柚子皮为原料,采用共沉淀法制备出磁性生物炭材料,考察了其处理模拟含油废水的性能,同时利用SEM、FT-IR和XRD等对其结构进行了表征。结果表明,所制备的磁性生物炭材料为柚子皮生物炭与Fe3O4的复合物,在这种复合物中Fe3O4得到均匀分布。该磁性材料为三维网状多孔结构,具有较大的比表面积与较好的磁性,易于分离和再生,有较好的除油性能与重复利用性能。在室温、反应时间为30 min、含油废水质量浓度为260 mg/L、磁性生物炭材料质量浓度为3 g/L时,材料的除油率可达83.9%,材料对废水中油的去除是生物炭和Fe3O4协同作用的结果。

Abstract

Magnetic biochar material is prepared by co-precipitation method with natural spent pomelo peel as raw agents.Its performance in treating with simulated oil-bearing wastewater is studied,and its structure is characterized by means of SEM,XRD,FTIR,and so on.Results show that the prepared magnetic biochar material is a compound of pomelo peel biochar and Fe3O4,in which Fe3O4 distributes uniformly.The magnetic material owns three-dimensional network structure with multi-pore,large specific surface and good magnetism,and it can be easily be separated from water and regenerated.It shows excellent oil-removal performance and regeneration property.The oil removal rate can reach 83.9% as reaction has performed for 30 min at room temperature,the concentration of oil-bearing wastewater is 260 mg·L-1,and the dosage of the magnetic material is 3 g·L-1.The removal of oil by this material is contributed to the synergistic effect of Fe3O4 and biochar.

关键词

生物炭 / 含油废水 / 磁性 / 柚子皮

Key words

biochar / oil-bearing wastewater / magnetism / pomelo peel

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磁性生物炭材料在含油废水处理中的应用研究[J]. 现代化工, 2021, 41(3): 149-153 DOI:10.16606/j.cnki.issn0253-4320.2021.03.030

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