以具有较高表面积的新鲜椰壳炭（SAC）为催化剂，采用盐酸和硝酸对SAC进行改性。考察改性前后的催化剂催化湿式过氧化物氧化（CWPO）降解间甲酚的反应效果。利用物理吸附、TPD-MS、拉曼光谱、XRF、SEM和XPS等对改性前后的催化剂进行表征。CWPO实验结果表明，活性炭催化剂表面含氧官能团（SOGs）在CWPO反应中发挥了重要作用，连续实验的情况下，硝酸处理的活性炭（SAC-N）表现出最佳的催化活性，反应1 800 h后间甲酚的转化率始终高达80%，平均TOC去除率达到25%以上。

Fresh coconut shell carbon (SAC) with high surface area is modified by hydrochloric acid and nitric acid.Catalytic wet peroxide oxidation (CWPO) degradation of m-cresol is investigated by SAC catalysts before and after modification,respectively.SAC catalysts before and after modification are characterized by physical adsorption,TPD-MS,Raman spectroscopy,X-ray fluorescence analysis (XRF),SEM and XPS.CWPO experimental results indicate that the surface oxygen-containing functional groups (SOGs) of SAC catalyst play an important role in CWPO reaction.Under continuous experiments,the activated carbon (SAC-N) treated by nitric acid shows the best catalytic activity,over which the conversion rate of m-cresol has always remained as high as 80% after 1 800 h of reaction,and the average removal rate of TOC exceeds 25%.

王蕊(1994-),女,硕士生,研究方向为污水处理,501976826@qq.com