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摘要
研究了RSV流程CO2冻堵机理和控制手段,RSV流程可以通过控制合理的工艺参数和设置预分离器的方式控制冻堵;分析了RSV流程和脱甲烷塔中CO2的分布规律,结果表明,控制凝液产品中CO2含量需要将脱甲烷塔下部的CO2气化并使得之进入上部;在RSV流程基础上,改进双塔RSVC流程,双塔设置可以实现脱甲烷塔顶气相对吸收塔底部液相中CO2进行汽提,提高吸收塔中的CO2浓度,设置预分离器可以在吸收塔气相中CO2含量升高后控制CO2冻堵。RSV和RSVC流程对比结果表明,RSVC流程在几乎不影响乙烷收率情况下,使凝液产品中的CO2含量能降低约2.4%。
Abstract
The mechanism and control methods of CO2 freezing blockage in recycle split vapor (RSV) process are studied.As for RSV process,CO2 freezing blockage can be controlled by controlling reasonable process parameters and setting a pre-separator.Distribution rules of CO2 in RSV process and demethanizer are analyzed.Results show that CO2 in the lower part of the demethanizer must be gasified and enter the upper part of that so as to control CO2 content in the condensate products.Based on the above results and RSV process,RSVC,a modified RSV process with double towers is proposed,in which CO2 in the liquid phase at the bottom of the absorption tower is stripped to concentrate CO2.A pre-separator is set to control CO2 freezing blockage once CO2 content in the gas phase of the absorption tower rises.Comparison between RSV and RSVC processes show that RSVC process can reduce CO2 content in the condensate products by 2.4% while it brings about little impact on the yield of ethane.
关键词
乙烷回收
/
凝液产品
/
流程改进
/
CO2冻堵
/
RSV流程
Key words
ethane recovery
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condensate products
/
process improvement
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CO2 freezing blockage
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RSV process
控制凝液产品中CO2含量的乙烷回收流程改进[J].
现代化工, 2021, 41(1): 219-223,226 DOI:10.16606/j.cnki.issn0253-4320.2021.01.044