基于电驱离子膜-分质结晶工艺的高盐废水资源化中试研究

陈天羽, 陈业刚, 黄天寅

现代化工 ›› 2020, Vol. 40 ›› Issue (12) : 206 -211.

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现代化工 ›› 2020, Vol. 40 ›› Issue (12) : 206-211. DOI: 10.16606/j.cnki.issn0253-4320.2020.12.043
工业技术

基于电驱离子膜-分质结晶工艺的高盐废水资源化中试研究

    陈天羽, 陈业刚, 黄天寅
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Pilot study on recycling high salt wastewater based on electric-driven ion membrane separation and segregation crystallization process

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摘要

以某化工企业高盐废水为处理对象后,设计构建了电驱离子膜-分质结晶试验装置进行耦合技术废水处理资源化研究。结果表明,高含盐工业废水通过该工艺处理钙镁离子去除96%以上,产品水水质各项指标均能够满足试验设计要求,产水率在71%左右。电驱离子膜系统可将TDS全部浓缩到200 000 mg/L以上,均可达到进水的6~8倍,盐回收率≥89%。试验期间硫酸钠产品盐均满足产品盐品质要求,氯化钠产品盐合格率偏低。该耦合技术可以实现零排放及资源化试验目的。

Abstract

An electric-driven ion membrane-segregation crystallization test device is designed and constructed to treat with high-salt wastewater in a certain chemical company to study the wastewater treatment recycling coupling technology.It is found from the results that the removal rate of calcium and magnesium ions from the high-salt wastewater by this coupling technology exceeds 96%,the quality indexes of the effluent water can meet the requirements of the test design,and the water yield is around 71%.The electric-driven ion membrane system can concentrate all TDS to more than 200 000 mg·L-1,which is equivalent to 6-8 times that of the inflow water,and the salt recovery rate surpasses 89%.During the test,the produced sodium sulfate meets the product salt quality requirements,and the produced sodium chloride shows a lower qualified rate.This coupling technology can achieve the purpose of zero emission and recycling test.

关键词

零排放 / 资源化 / 分质结晶 / 电驱离子膜 / 高盐废水

Key words

zero emission / recycling / segregation crystallization / electric-driven ion membrane / high-salt wastewater

Author summay

陈天羽(1992-),男,硕士生

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基于电驱离子膜-分质结晶工艺的高盐废水资源化中试研究[J]. 现代化工, 2020, 40(12): 206-211 DOI:10.16606/j.cnki.issn0253-4320.2020.12.043

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