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摘要
采用两步水热法制备α-MnO2/Mn2O3/AISI304丝网整体式催化剂,首先通过尿素水热法在AISI304丝网上生长Mn2O3涂层;然后在涂层表面原位生成以α-MnO2为活性组分的催化剂。利用XRD、SEM、N2吸附-脱附、H2-TPR等对催化剂进行表征,考察了不同焙烧温度对整体式催化剂结构和碳烟催化燃烧性能的影响。结果表明,焙烧温度为700℃时,Mn-Nit-700的活性组分以α-MnO2纳米棒为主,具有更加丰富的表面活性氧物种(焙烧温度<500℃),有利于碳烟的催化燃烧反应。在O2/N2氛围下,Mn-Nit-700催化剂的催化燃烧碳烟性能最佳(T50=388℃),CO2选择性为100%,同时具有较佳的抗水性能。
Abstract
A two-step hydrothermal method is utilized to prepare α-MnO2/Mn2O3/AISI304 wire-mesh monolithic catalyst.Firstly,Mn2O3 coating grows on AISI304 wire-mesh through urea hydrothermal method,then the catalyst with α-MnO2 as active component generates in situ on the coating surface.The as-prepared catalyst is characterized by XRD,SEM,N2 adsorption-desorption,and H2-TPR,et al.Effects of different roasting temperatures on the monolithic catalyst's structure and catalytic combustion performance for soot are investigated.It is shown that α-MnO2 nanorods are the main active components of Mn-Nit-700 when the roasting temperature is 700℃.Mn-Nit-700 has more abundant surface active oxygen species (<500℃),which is beneficial to the catalytic combustion of soot.In an O2/N2 atmosphere,Mn-Nit-700 catalyst shows the best catalytic performance for soot combustion (T50=388℃) with excellent water tolerance,and CO2 selectivity can reach 100%.
关键词
整体式催化剂
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α-MnO2
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焙烧温度
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碳烟
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催化燃烧
Key words
monolithic catalyst
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α-MnO2
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roasting temperature
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soot
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catalytic combustion
α-MnO2/Mn2O3/AISI304丝网整体式催化剂的制备及催化燃烧碳烟性能研究[J].
现代化工, 2020, 40(11): 173-177 DOI:10.16606/j.cnki.issn0253-4320.2020.11.036