PDF (3733K)
摘要
为提高锂离子电池负极材料的电催化析氢性能,以石墨烯为载体,采用水热法制备了还原氧化石墨烯(RGO)纳米片负载WS2、SnS2复合纳米材料。电化学性能测试结果表明,当SnS2与WS2的物质的量的比为1:2、电流密度为10 mA/cm2时,其在0.5 mol/L的H2SO4电解质溶液中的过电位为180 mV,Tafel斜率为129 mV/dec。SnS2/RGO/WS2复合纳米材料作为无贵金属的电催化剂具有巨大的潜力。
Abstract
In order to improve the electrocatalytic hydrogen evolution performance of anode materials of lithium ion battery,the reduced graphene oxide (RGO) nanosheets loaded with WS2 and SnS2 composite nanomaterials are prepared via a simple hydrothermal method by using graphene as a carrier.The results from electrochemical performance test show that the overpotential of the prepared composite in a 0.5 mol·L-1 H2SO4electrolyte solution is 180 mV and its Tafel slope is 129 mV·dec-1 when the mass ratio of SnS2 to WS2 is 1:2,and the current density is 10 mA·cm-2.The environmentally friendly synthesis method and excellent performance show that SnS2/RGO/WS2 composite nanomaterial has a great potential as an electrocatalyst without precious metals.
关键词
石墨烯
/
析氢反应
/
水热法
/
二硫化锡
/
二硫化钨
Key words
graphene
/
hydrogen evolution reaction
/
hydrothermal method
/
tin disulfide
/
tungsten disulfide
Author summay
祁佳音(1994-),女,硕士研究生,研究方向为电化学析氢,2449877351@qq.com
SnS2/RGO/WS2复合材料的制备及其催化性能的研究[J].
现代化工, 2020, 40(11): 159-163 DOI:10.16606/j.cnki.issn0253-4320.2020.11.033