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摘要
综述了近年来酚类化合物加氢脱氧催化剂的研究进展,分析了代表性酚类化合物的特点及其HDO所涉及的反应。对比分析了金属催化剂、硫化物催化剂、磷化物催化剂、碳化物和氮化物催化剂对酚类化合物HDO反应的催化性能。此外,对酚类化合物HDO催化剂载体的发展状况进行了介绍,指出了催化剂载体的发展趋势。最后总结了各类催化剂的特性,归纳了催化剂对酚类化合物HDO产物的影响及载体在酚类化合物HDO反应中的作用,并对下一步酚类化合物HDO催化剂的发展方向进行了展望。
Abstract
Research progress in catalysts for hydrodeoxygenation (HDO) of phenolic compounds in recent years is reviewed.The characteristics of representative phenolic compounds and the involved reactions in their HDO are analyzed.The catalytic performances of metals,sulfides,phosphides,carbides and nitrides catalysts in HDO of phenolic compounds are compared and analyzed.In addition,the development status of the support of catalyst for HDO of phenolic compounds is introduced,and the development trend of support is pointed out.Finally,the characteristics of various catalysts are summarized,the influence of catalysts on the products from HDO of phenolic compounds is summed up and the role of support in HDO reaction is reported.Relating development direction for HDO catalyst in the future is also prospected.
关键词
加氢脱氧
/
载体
/
催化剂
/
酚类化合物
Key words
hydrodeoxygenation
/
support
/
catalyst
/
phenolic compounds
酚类化合物加氢脱氧催化剂的研究进展[J].
, 2020, 40(10): 66-70 DOI:10.16606/j.cnki.issn0253-4320.2020.10.014