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摘要
以GaNO3为改性剂,采用浸渍法对ZSM-5催化剂进行改性。利用XRD、FT-IR、SEM等手段对改性前后催化剂进行表征,并进行催化性能评价。结果表明,使用2-Ga-ZSM-5催化剂进行反应,小桐子油的转化率为37.22%,液体产物酸值为1.67 mg(KOH)/g,皂化值为8.94 mg(KOH)/g;液体产物主要成分为芳香族化合物,质量分数为96.03%。
Abstract
ZSM-5 catalyst is modified by impregnation method using GaNO3 as a modifier.Before and after modification,the catalysts are respectively characterized by XRD,FT-IR and SEM,and their catalytic performances are evaluated.The results show that 2-Ga-ZSM-5 catalyst is the best one,over which the conversion of Jatropha curcas oil can reach 37.22%,the acid value of liquid product is 1.67 mgKOH·g-1 and the saponification value is 8.94 mgKOH·g-1.The main components of liquid product is an aromatic compound,with a content of 96.03%.
关键词
Ga-ZSM-5
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催化裂化
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小桐子油
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改性
Key words
Ga-ZSM-5
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catalytic cracking
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Jatropha curcas oil
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modification
Author summay
姚志松(1995-),男,硕士研究生,主要从事生物质能转换与利用方面的研究,yaozhisong818@163.com
Ga改性ZSM-5催化剂催化裂化小桐子油的研究[J].
, 2020, 40(9): 85-88 DOI:10.16606/j.cnki.issn0253-4320.2020.09.018