沉淀+反渗透+纳滤技术处理氯化钛渣废水中试研究

王慧雅

现代化工 ›› 2020, Vol. 40 ›› Issue (7) : 211 -216.

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现代化工 ›› 2020, Vol. 40 ›› Issue (7) : 211-216. DOI: 10.16606/j.cnki.issn0253-4320.2020.07.045
工业技术

沉淀+反渗透+纳滤技术处理氯化钛渣废水中试研究

    王慧雅
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Pilot study on treatment of titanium chloride slag wastewater by precipitation/reverse osmosis/nanofiltration

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摘要

设计了一套集重金属去除、氯化钠回收、大量固体废物再利用为一体的工艺并进行中试研究。调节pH至6~7和9~10可分别去除大部分Cu2+、Sn2+、Fe3+、Zn2+、Pb2+、Mg2+等重金属离子,再串联反渗透和纳滤工艺,控制浓缩倍数5.3左右时截留率分别为97.7%和99.7%,终端串联的二级纳滤使NaCl浓度达到79 092.5 mg/L。通过实验分析可知,该工艺可对溶液进行提纯、富集,使溶液中的氯化钠浓度、纯度均达到相应标准,从而实现氯化钠的回收利用。

Abstract

A technology integrating with removing heavy metal,recovering sodium chloride and reusing large amount of solid waste is designed,and pilot study is carried out for it.Most of heavy metal ions such as Cu2+,Sn2+,Fe3+,Zn2+,Pb2+ and Mg2+ can be removed by adjusting pH to 6-7 and 9-10,respectively,and then reverse osmosis and nanofiltration in series.The enterception rate reaches 97.7% after reverse osmosis and reaches 99.7% finally as the concentration multiple is controlled at around 5.3.NaCl concentration can reach 79 092.5 mg·L-1 due to the second-stage nanofiltration in series terminal.Through the experimental analysis,it can be known that this process can purify and enrich the solution,and make the concentration and purity of sodium chloride in the solution reach the corresponding standards,so as to realize the recovery and utilization of sodium chloride.

关键词

氯化钛渣 / 回收利用 / 纳滤 / 反渗透

Key words

chloride titanium slag / recycle / nanofiltration / reverse osmosis

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沉淀+反渗透+纳滤技术处理氯化钛渣废水中试研究[J]. 现代化工, 2020, 40(7): 211-216 DOI:10.16606/j.cnki.issn0253-4320.2020.07.045

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