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摘要
以不同长度烷烃取代靛红和联苯胺为底物合成了新型凝胶因子,通过FT-IR、NMR等表征方法对凝胶因子的结构进行了分析,研究了产物DICB-n(n=10、12、16)在不同有机溶剂中的凝胶性能。结果表明,DICB-10、DICB-12可在二甲基亚砜(DMSO)中形成稳定凝胶,产物凝胶性能优良;产物DICB-10对钴离子可产生特异性响应。通过刺激响应性质测试实验可知,凝胶作为一种软物质对机械力和热可产生结构上的变化,在智能材料领域具有潜在的应用前景。
Abstract
A new kind of gelator is synthesized based on benzidine and isatin with different length of alkyl chain,the structure of the gelator is characterized by FT-IR and H NMR spectra.The gel ability of the gelator is explored in different solvents.Results show that DICB-10,DICB-12 gelators can form stable gels in DMSO,and the performance of gels products are good.DICB-10 can generate specific response to cobalt ions.As a soft material,gel can change its structure in response to mechanical force and heat,which makes gel have potential application.
关键词
凝胶因子
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特异性响应
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钴离子
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联苯胺
Key words
gelator
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specific response
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cobalt ion
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benzidine
Author summay
任兴栋(1993-),男,硕士研究生,研究方向为小分子凝胶因子,81252440@qq.com
新型凝胶因子的凝胶性能及离子响应研究[J].
现代化工, 2020, 40(7): 171-174,179 DOI:10.16606/j.cnki.issn0253-4320.2020.07.036