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摘要
以塑料为原料、改性煤矸石为模板,在管式炉中用KOH进行活化制备多孔碳材料(PCM)。利用SEM、FT-IR、XRD和氮气吸-脱附对样品的形貌、成分及孔结构进行表征,并以亚甲基蓝(MB)为模拟污染物研究碳材料的吸附性能。结果表明,10 mg PCM在240 min内可使初始质量浓度为100 mg/L的MB几乎完全吸附,吸附量达498.35 mg/g,降解率达99.67%。对吸附过程进行拟合后得出,准二级动力学模型可以更好地描述该吸附过程,吸附等温模型符合Langmuir吸附等温模型。
Abstract
Porous carbon material (PCM) is prepared by using plastics as raw material,modified gangue as template and performing activation with KOH in a tube furnace.The morphology,composition and pore structure of PCM samples are characterized by SEM,FT-IR,XRD and nitrogen adsorption-desorption,and the absorptive performance is studied through using methylene blue as simulated pollutant.It is shown that the prepared PCM has a spheroidal structure,and the specific surface area and total pore volume of the activated material are 535.210 7 m2·g-1 and 0.367 5 cm3·g-1 respectively.The adsorption properties of carbon materials are studied by using methylene blue (MB) as a simulated pollutant.The results show that 10 mg of PCM can almost completely absorb MB with an initial concentration of 100 mg·L-1 in 240 min,with an adsorption capacity of 498.35 mg·g-1 and a degradation rate of 99.67%.After fitting the adsorption process,the quasi-secondary kinetic model can better describe the adsorption process,and the adsorption isothermal model is more in line with Langmuir adsorption isotherm model.
关键词
塑料
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吸附
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亚甲基蓝
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多孔碳材料
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改性煤矸石
Key words
plastic
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adsorption
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methylene blue
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porous carbon material
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modified gangue
Author summay
张晓婉(1993-),女,硕士研究生,研究方向为无机材料,zhangxiaowanzbdx@163.com
混合塑料与改性煤矸石模板制备多孔碳材料及其吸附性能的研究[J].
现代化工, 2020, 40(5): 194-198 DOI:10.16606/j.cnki.issn0253-4320.2020.05.042