灰分对玉米芯基活性炭电化学性能的影响

王芳平, 张劲斌, 李晨阳, 罗英涛, 杜娟, 汪艳芳

现代化工 ›› 2020, Vol. 40 ›› Issue (5) : 190 -193.

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现代化工 ›› 2020, Vol. 40 ›› Issue (5) : 190-193. DOI: 10.16606/j.cnki.issn0253-4320.2020.05.041
科研与开发

灰分对玉米芯基活性炭电化学性能的影响

    王芳平, 张劲斌, 李晨阳, 罗英涛, 杜娟, 汪艳芳
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Effect of ash on electrochemical performance of corncob-based activated carbon

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摘要

采用填埋法将玉米芯进行炭化,炭化物经过脱灰处理后在碱炭比为4:1、温度为850℃的条件下进行活化,制备得到玉米基活性炭(CAC)。CAC经过深度脱灰制备得到CAC-T,CAC-T的比表面积从脱灰前的3 250 m2/g增加到3 487 m2/g。采用循环伏安、交流阻抗和恒流充放电对CAC、CAC-T的电化学性能进行测试,结果表明,CAC-T在电流密度为1 A/g时的单电极比容量为256.1 F/g,10 000次充放电后容量仍保持在255.8 F/g,容量保持率高达99.9%。

Abstract

Corncob is carbonized by landfill method,and ash removal is performed for the carbonized products.Corncob-based activated carbon (CAC) is prepared under the conditions that the ratio of KOH to corncob-based carbon after removing ash is 4,and the activation temperature is at 850℃.CAC-T is obtained from CAC through deeply deashing.The specific surface area of CAC-T increases to 3 487 m2·g-1 from the 3 250 m2·g-1 of CAC.The electrochemical performances of CAC and CAC-T are tested with cyclic voltammetry (CV),electrochemical impedance spectroscopy (EIS) and galvanostatic charge-discharge.The results show that the specific capacitance of single CAC-T electrode is about 256.1 F·g-1 at a charge-discharge current density of 1 A·g-1.After 10 000 charge-discharge cycles,the specific capacitance of CAC-T electrode maintains at around 255.8 F·g-1.The capacitance retention is as high as 99.9%.

关键词

玉米芯 / 电化学性能 / 活性炭 / 灰分

Key words

corn-cob / electrochemical performance / activated carbon / ash content

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灰分对玉米芯基活性炭电化学性能的影响[J]. 现代化工, 2020, 40(5): 190-193 DOI:10.16606/j.cnki.issn0253-4320.2020.05.041

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