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摘要
利用反相微乳液法合成了一种清洁压裂液用反相微乳液型稠化剂BCG-1R。BCG-1R在水中起黏时间短,配制时不会出现结团和"鱼眼"现象,得到的压裂液均匀。由该稠化剂和配套添加剂配制而成的压裂液的抗温能力可达160℃,具有良好的耐温耐剪切性能和悬砂性能。压裂液完全破胶后呈半透明状,表面张力低至25.86 mN/m,几乎无残渣(4 mg/L以下)。破胶液与实验室的原油样品4 h内破乳率可达100%。针对某实测温度为118.6℃的油井,采用连续混配法并以BCG-1R为稠化剂配制的压裂液进行压裂施工,施工后增产效果良好。
Abstract
BCG-1R,a kind of reverse phase micro-emulsion thickening agent for clean fracturing fluid,is synthesized by means of reverse-phase micro-emulsion method.BCG-1R can be dissolved in water for a short time.When it is used to prepare fracturing fluid,there will be no agglomeration and "fisheye" phenomena.The obtained fracturing fluid from BCG-1R and matching additives is uniform,has a good temperature resistance as high as 160℃ and shows good temperature-tolerate and shear-tolerate properties as well as good sand suspension ability.It also has low friction resistance.After the fracturing fluid is broken,gel breaking liquid is translucent with a surface tension as low as 25.86 mN·m-1 and has hardly residue (less than 4 mg·Lm-1).The gel breaking liquid's demulsification rate to crude oil from Yanchang Oilfield can reach 100% within 4 h.The fracturing fluid that is prepared by continuous blending method with BCG-1R as thickening agent is used in an oil well with a temperature of 118.6℃,an excellent production enhancement effect has been achieved.
关键词
反相微乳液聚合
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连续混配
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低残渣
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耐温耐剪切
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清洁压裂液
Key words
reverse phase micro-emulsion polymerization
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continuous blending
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low residue
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temperature-tolerate and shear-tolerate properties
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clean fracturing fluid
Author summay
魏俊(1988-),男,工程硕士,工程师,研究方向为压裂改造,553044317@qq.com
反相微乳液型聚合物压裂液的研究及应用[J].
现代化工, 2020, 40(1): 111-114,119 DOI:10.16606/j.cnki.issn0253-4320.2020.01.024