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摘要
采用Mg (OH)2预填充PAN基膜为前驱体制备了具有多级孔结构的复合碳材料,制备的复合碳材料含有54.1% C、26.8% O、6.2% N和6.5% Mg,可将其用作超级电容器的电极材料和染料吸附剂使用。作为超级电容器时,比电容在1 A/g扫描速率下可达236 F/g,在10 A/g扫描速率下可达206 F/g左右,比电容保持率高达87%。优良的倍率性能与多孔结构的层次性有关。该复合材料作为染料吸附剂使用时,对甲基橙(MO)有很高的吸附能力,当染料质量分数为800 μg/g时,其饱和吸附量可达1 170 mg/g。
Abstract
Carbonaceous composite with hierarchically porous structure is prepared by using Mg(OH)2 pre-filled PAN-based membrane precursor for the first time.The prepared carbonaceous composite contains 54.1% of C,26.8% of O,6.2% of N and 6.5% of Mg.The composite is used as electrode material of super capacitor and dye adsorbent.As it is used to make electrode material for super capacitor,the specific capacitance reaches 236 F·g-1 at a scanning rate of 1 A·g-1,and about 206 F·g-1 at a scanning rate of 10 A·g-1.The retention rate of specific capacitance is as high as 87%.Such an excellent ratio performance is related to the hierarchy of porous structure.As the carbonaceous composite is used as a dye adsorbent,it shows a high adsorption capacity to methyl orange.The saturated adsorption capacity can reach about 1,170 mg·g-1 when the mass content of methyl orange is 800 μg·g-1.The present study provides a simple method to prepare the novel carbonaceous composite for different applications.
关键词
纳米复合材料
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吸附
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染料
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超级电容器
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碳材料
Key words
nanocomposite
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adsorption
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dye
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super capacitor
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carbon material
Author summay
刘振盈(1993-),女,硕士研究生,研究方向为分离膜的制备及应用,1825387519@qq.com
PAN-Mg (OH)2多孔复合碳材料的制备及其在染料吸附和超级电容器中的应用[J].
现代化工, 2019, 39(12): 180-185 DOI:10.16606/j.cnki.issn0253-4320.2019.12.038