氧化锌/石墨烯复合物的固相制备及气敏、光催化应用

郎大宁, 李怡招, 曹亚丽, 贾殿赠

现代化工 ›› 2019, Vol. 39 ›› Issue (12) : 130 -134.

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现代化工 ›› 2019, Vol. 39 ›› Issue (12) : 130-134. DOI: 10.16606/j.cnki.issn0253-4320.2019.12.028
科研与开发

氧化锌/石墨烯复合物的固相制备及气敏、光催化应用

    郎大宁, 李怡招, 曹亚丽, 贾殿赠
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Solid-phase synthesis of ZnO/graphene nanocomposites and their gas sensing and photocatalytic properties

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摘要

通过室温固相法制得氧化锌/石墨烯(ZnO/G)复合材料,并利用X射线衍射仪、透射电子显微镜和荧光光谱仪等对复合材料进行表征。考察了ZnO/G复合材料的气敏和光催化性能,并与ZnO进行了比较。结果表明,将ZnO/G复合材料制成气敏元件,其比ZnO对于乙醇蒸汽有更高的响应灵敏度和较好的选择性。复合材料对水溶液中罗丹明B也有较好的光降解性能,在紫外光照射80 min后,其对染料有机物的降解率达94%以上,优于纳米ZnO。

Abstract

ZnO/graphene (ZnO/G) nanocomposite is prepared by a solid-phase reaction method at room temperature.The structure of the product is characterized by XRD,TEM,and fluorescence spectrometer.The gas-sensitive and photocatalytic properties of ZnO/G nanocomposite are studied and compared with that of ZnO nanoparticles.It is shown that ZnO/G nanocomposite is superior to ZnO nanoparticles.A gas sensor is made from ZnO/G nanocomposite,which exhibits higher response sensitivity and better selectivity to ethanol vapor than that made from ZnO.The nanocomposite shows a good photodegradation to Rhodamine B in aqueous solution.After taking UV irradiation for 80 min,the degradation rate of RhB ZnO/G nanocomposite exceeds 94%,better than that of ZnO.

关键词

室温固相反应 / 光催化 / 气敏 / 氧化锌/石墨烯复合物

Key words

room-temperature solid-state reaction / photocatalysis / gas sensor / ZnO/graphene nanocomposite

Author summay

郎大宁(1996-),女,硕士研究生,研究方向为纳米材料在环境方面的应用,15894607930@163.com

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氧化锌/石墨烯复合物的固相制备及气敏、光催化应用[J]. 现代化工, 2019, 39(12): 130-134 DOI:10.16606/j.cnki.issn0253-4320.2019.12.028

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