Al2O3负载型Cu-Al类水滑石氧化物的NOx吸附及分解性能

拜文磊, 刘伟军, 郝再兵, 张博儒, 张书华

现代化工 ›› 2019, Vol. 39 ›› Issue (5) : 137 -140,142.

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现代化工 ›› 2019, Vol. 39 ›› Issue (5) : 137-140,142. DOI: 10.16606/j.cnki.issn0253-4320.2019.05.030
科研与开发

Al2O3负载型Cu-Al类水滑石氧化物的NOx吸附及分解性能

    拜文磊, 刘伟军, 郝再兵, 张博儒, 张书华
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Performance of Al2O3 loaded Cu-Al hydrotalcite-like oxides in adsorption and decomposition of NOx

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摘要

采用水热法制备铜铝水滑石作为前体,经500℃焙烧得到Cu-Al复合氧化物,并利用X射线衍射、红外光谱对其进行表征;将Cu-Al复合氧化物负载于直径为3~5 mm球状Al2O3载体上,进行NO吸附和热稳定性试验。结果表明,NO、O2、H2O(g)在Cu-Al复合氧化物作用下在氧化物表面生成HNO3,并与Cu-Al复合氧化物中的CuO组分反应生成Cu(NO32,吸附率可达28%,再高温焙烧可以释放以NO为主体的氮氧化物,并且可以恢复到之前的金属氧化物结构。而吸附完成的化合物静置数天后会回到原来的水滑石层状结构。

Abstract

Copper-aluminum hydrotalcite is made via hydrothermal method,then is roasted at 500℃ to prepare Cu-Al complex oxides that is characterized by X-ray diffraction and infrared-red spectrum.The prepared Cu-Al composite oxide is loaded onto the surface of spherical Al2O3 carrier with a diameter between 3 mm and 5 mm,and the sample is evaluated in the experiments about NO adsorption and heat endurance.The experimental results show that NO,O2 and water steam forms HNO3 on the surface of Cu-Al complex oxides,then HNO3 reacts with CuO in Cu-Al composite oxides to form Cu(NO3)2,and the adsorption efficiency can reach 28%.NOx,with NO as the main body,can be released when the product is roasted at a high temperature,and the structure of the former metal oxides can be restored.The adsorbed compounds will return to the original hydrotalcite-like layered structure after a few days of static storage.

关键词

铜铝水滑石 / 催化剂再生 / NOx吸附 / 铜铝氧化物 / Al2O3载体

Key words

Cu-Al hydrotalcite / regeneration of catalyst / NOx adsorption / Cu-Al oxide / Al2O3 carrier

Author summay

拜文磊(1994-),男,硕士研究生,研究方向为尾气处理,424084694@qq.com

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Al2O3负载型Cu-Al类水滑石氧化物的NOx吸附及分解性能[J]. 现代化工, 2019, 39(5): 137-140,142 DOI:10.16606/j.cnki.issn0253-4320.2019.05.030

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