氮掺杂碳包覆高倍率钛酸锂材料的制备

陈垒, 陈振宇, 许益伟, 司聪玲, 丁亚西, 陈晓梅

现代化工 ›› 2019, Vol. 39 ›› Issue (4) : 174 -177.

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现代化工 ›› 2019, Vol. 39 ›› Issue (4) : 174-177. DOI: 10.16606/j.cnki.issn0253-4320.2019.04.039
科研与开发

氮掺杂碳包覆高倍率钛酸锂材料的制备

    陈垒, 陈振宇, 许益伟, 司聪玲, 丁亚西, 陈晓梅
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Preparation of nitrogen-doped carbon-coated high-rate Li4Ti5O12 materials

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摘要

以三聚氰胺为氮源合成了氮掺杂改性的钛酸锂(LTO-0.1N)材料,并通过扫描电子显微镜(SEM)和激光颗粒粒度分析检测材料的微观形貌和宏观颗粒。结果表明,与原始的LTO相比,合成的N掺杂LTO-0.1N样品显著改善了其电化学性质。LTO-0.1N的放电比容量在0.2 C时为172 mAh/g,在10 C时为120 mAh/g;LTO在0.2 C时为150 mAh/g,10 C时为98 mAh/g。氮掺杂改性的LTO-0.1N材料的电荷转移阻抗为375.58 Ω,没有改性的LTO的电荷转移阻抗为2 008.27 Ω。电荷转移阻抗的显著减小是氮掺杂改性LTO-0.1N材料电化学性能提高的原因之一。

Abstract

A nitrogen-doped modified lithium titanate (LTO-0.1N) material is synthesized using melamine as a nitrogen source,and its microscopic morphology and macroscopic particles are detected by scanning electron microscopy (SEM) and laser particle size analysis.The results show that the synthesized N-doped LTO-0.1N sample shows significantly-improved electrochemical properties compared to the original LTO.The discharge specific capacity of LTO-0.1N is 172 mAh·g-1 at 0.2 C and 120 mAh·g-1 at 10 C,that for LTO is 150 mAh·g-1 at 0.2 C and 98 mAh·g-1 at 10 C.The charge transfer impedance of the N-doped modified LTO-0.1N material is 375.58 Ω,and that of the unmodified LTO is 2 008.27 Ω.A significant reduction in charge transfer resistance may be one of the reasons for the improved electrochemical performance of nitrogen doped modified LTO-0.1N material.

关键词

钛酸锂 / 导电性 / 碳包覆 / 氮掺杂

Key words

lithium titanate / conductivity / carbon coated / nitrogen doped

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氮掺杂碳包覆高倍率钛酸锂材料的制备[J]. 现代化工, 2019, 39(4): 174-177 DOI:10.16606/j.cnki.issn0253-4320.2019.04.039

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