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摘要
采用水热法制备一维WO3微米棒,并以其为模板利用Fe3+水解成功制备出具有三维结构的WO3/FeOOH复合材料。利用X射线衍射(XRD)、X射线光电子能谱仪(XPS)、场发射扫描电子显微镜(FESEM)、电化学测试等手段对材料的结构、组成以及电化学性能进行了表征。结果表明,WO3/FeOOH复合材料作为超级电容器材料具有优异的电化学性能。电流密度为0.5 A/g时,比容量高达296.7 F/g;电流密度为10 A/g时,比容量为171.7 F/g。并且在电流密度为10 A/g时循环1 000次后,其比容量保持率为92.3%。
Abstract
One-dimensional WO3 microrods are prepared via hydrothermal method and are used as template to prepare three-dimensional WO3/FeOOH composites by means of Fe3+ hydrolysis.The structure,composition and electrochemical properties of the composites are characterized by XRD,XPS,FESEM and electrochemical tests.The results show that WO3/FeOOH composites has excellent electrochemical performance and can be used as materials for supercapacitors.It has a specific capacity of 296.7 F·g-1 at a current density of 0.5 A·g-1,and a capacity of 171.7 F·g-1 at a current density of 10 A·g-1.Its specific capacity retention remains 92.3% after 1,000 cycles at a current density of 10 A·g-1.
关键词
WO3
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超级电容器
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WO3/FeOOH
Key words
WO3
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supercapacitor
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WO3/FeOOH
WO3/FeOOH的制备与电化学性能研究[J].
现代化工, 2018, 38(11): 183-185 DOI:10.16606/j.cnki.issn0253-4320.2018.11.039