为了扩展传统铜锌铝催化剂在车载甲醇自热式重整（ATRM）制氢过程中的应用，采用反向共沉淀法制备了不同铜锌摩尔比的铜锌铝氧化物催化剂，并与工业铜锌铝催化剂SCST-401进行比较。结果发现，该类催化剂的性能随着铜锌摩尔比的增加而提高。其中，Cu₃₀Zn₁₀Al催化剂在200~600℃范围内具有最佳的ATRM反应性能，而不含铜的催化剂Zn₄₀Al在500~600℃高温下具有与Cu₂₀Zn₂₀Al和Cu₁₀Zn₃₀Al相近的活性。此外，Cu₃₀Zn₁₀Al催化剂与商用催化剂SCST-401的甲醇转化率也相近，但前者铜的摩尔分数却远小于后者，且性能更稳定。在200~300℃的低温下其ATRM反应表现出更高的活性。

To study the feasibility of using conventional CuZnAl-oxides as catalysts for on-board hydrogen production by autothermal reforming of methanol (ATRM),CuZnAl-oxides catalyst with different copper-zinc ratios are prepared via reverse co-precipitation method.The samples are compared with commercial CuZnAl catalyst SCST-401.It is found that the performance of such type of catalysts improves with the increased mole ratio of copper to zinc.The prepared Cu₃₀Zn₁₀Al catalyst shows the best performance for ATRM in the range of 200-600℃,while Zn₄₀Al catalyst is found to have the similar activity with those of Cu₂₀Zn₂₀Al and Cu₁₀Zn₃₀Al at the temperature from 500℃ to 600℃.In addition,Cu₃₀Zn₁₀Al catalyst can bring about similar methanol conversion with that brought by commercial catalyst SCST-401 that has a much higher copper content than Cu₃₀Zn₁₀Al.Cu₃₀Zn₁₀Al exhibits more stable than SCST-401.Furthermore,Cu₃₀Zn₁₀Al shows higher activity for ATRM at low temperature from 200℃ to 300℃.

黄骁(1991-),男,硕士研究生,研究方向为节能减排,xmu_huangxiao@163.com