以骨架镍为催化剂，研究了α-蒎烯固定床连续加氢制顺式蒎烷工艺。考察了H₂压力、反应温度、物料空速及H₂用量等条件对反应的影响，优化了工艺条件。结果表明，在H₂压力为2 MPa、反应温度为120℃、液时空速为0.75 h^-1、氢气与α-蒎烯摩尔比为20时，α-蒎烯的转化率达99.3%，顺式蒎烷的选择性为92.6%。连续运行结果表明该工艺具有较好的稳定性。

Continuous hydrogenation of α-pinene in fixed-bed reactor to make cis-pinane are studied by using skeleton Ni catalyst.The effects of H₂ pressure, reaction temperature, space velocity of α-pinene and H₂ dosage on the hydrogenation are investigated.The optimized conditions for hydrogenation are as follows:H₂ pressure is 2 MPa, reaction temperature is at 120℃, LHSV of α-pinene is 0.75 h^-1 and the ratio of H₂ to α-pinene is 20.Under the optimal conditions, the conversion rate of α-pinene can reach 99.3% and the selectivity of cis-pinane can reach 92.6%.In addition, the result of continuous hydrogenation shows that this process is very stable.

陈川(1982-),女,硕士研究生,研究方向为非均相催化,8000000705@czie.edu.cn。