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摘要
以中海油环烷基常二线和减三线馏分油及其混合油作为原料,通过高压加氢处理、糠醛精制组合工艺制备变压器油和环保橡胶油。结果表明,常二线馏分油单独进料,通过单段高压加氢处理工艺可得到满足GB 2536—2011的变压器油。减三线馏分油单独进料,通过单段高压加氢处理工艺可直接生产CA为10%的环保橡胶油。2种馏分油混合进料,通过高压加氢处理和糠醛精制组合工艺可生产CA超过25%的高芳环保橡胶油,生产的变压器油CA较高,与深度精制石蜡基变压器油调和可得到满足GB 2536—2011的变压器油。2种馏分油混合进料可避免因原料切换产生过渡油,充分释放加工能力,提高装置利用率。
Abstract
The transformer oil and environmental friendly oil both with high CA value can be produced via high pressure hydrogenation combining with furfural refining process by using CNOOC-made naphthenic atmospheric 2# line and vacuum 3# line distillates as raw materials.It is found from the research results that atmospheric 2# line distillate alone can be processed by single stage high pressure hydrogenation method into transformer oil than can meet GB 2536-2011,vacuum 3# line distillate alone can be processed by single stage high pressure hydrogenation method to produce environmental friendly rubber oil with a CA value of 10%.The high aromatic hydrocarbons-containing environmental friendly rubber oil with a CA value more than 25% can be produced by the combined process with hydrogenation and furfural refining,using mixed atmospheric 2# line and vacuum 3# line distillate as raw materials.The combined process with mixed distillates fed can produce transformer oil with high CA value,which can be blended with deep refining paraffin-based transformer oil to meet GB 2536-2011 standard.The mixed distillate feed can avoid the production of transition oil caused by raw material switching,utilize fully the processing capacity and improve the utilization rate of facility.
关键词
常二线馏分油
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橡胶油
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变压器油
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综合加工
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减三线馏分油
Key words
atmospheric 2# line distillate
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rubber oil
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transformer oil
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comprehensive processing
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vacuum 3# line distillate
常二线和减三线馏分油综合加工的可行性研究[J].
现代化工, 2018, 38(8): 202-205 DOI:10.16606/j.cnki.issn0253-4320.2018.08.044