以聚苯乙烯微球为模板制备蜂窝状多孔石墨烯为载体，分别以过硫酸铵和β-MnO₂为氧化剂，采用化学原位聚合的方法制备合成多孔石墨烯/聚苯胺超级电容器材料。并利用X射线衍射（XRD）、比表面积分析仪（BET），扫描电子显微镜（SEM）、傅里叶红外光谱仪（FT-IR）和电化学工作站等对其微观形态、结构组成和电化学性质进行检测分析。结果表明：制备的载体材料具有蜂窝状结构，且以β-MnO₂为氧化剂的电容器材料具有良好的电化学性能。

Firstly,porous honeycomb graphene is prepared by using polystyrene microspheres as template.Then the porous graphene/PANI supercapacitor materials are synthesized by in-situ polymerization in the dispersion system of porous honeycomb graphene and using ammonium persulfate and β-MnO₂ respectively as oxidant.The micromorphologym structure,composition and electrochemical performance of the materials are characterized by X-ray diffraction spectroscopy (XRD),Brunauer-Emmett-Teller (BET),scanning electron microscopy (SEM),Fourier transform infrared spectroscopy (FT-IR) and electrochemical workstation.The results show that the prepared carrier material has a honeycomb structure and the porous graphene/PANI materials using β-MnO₂ as oxidant have better electrochemical properties.