现代化工

现代化工 ›› 2017, Vol. 37 ›› Issue (7) : 19-22,24. DOI: 10.16606/j.cnki.issn0253-4320.2017.07.005

技术进展

原子转移自由基聚合工业化技术研究进展

朱建军, 唐华东

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Research progress in the industrialization of atom transfer radical polymerization

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摘要

介绍了近年来原子转移自由基聚合在实现工业化过程中的工作和进展，包括：聚合物后处理方法、负载型催化剂、离子液体中ATRP、非铜系催化剂体系、新型ATRP聚合方式以及ATRP促进剂等，同时对未来如何实现ATRP工业化进行了展望。

Abstract

Progresses on the industrialization of atom transfer radical polymerization (ATRP) in recent years are introduced,including post-polymerization purification,immobilized catalyst,ATRP in ionic liquid,non-copper catalyst system,novel ATRP methods,and ATRP promoters.And the future way to achieve the industrialization of ATRP is prospected.