CoPC/g-C3N4的制备及其光催化降解苯酚性能研究

贾建岗, 何淑媛

现代化工 ›› 2024, Vol. 44 ›› Issue (10) : 180 -185.

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现代化工 ›› 2024, Vol. 44 ›› Issue (10) : 180-185. DOI: 10.16606/j.cnki.issn0253-4320.2024.10.033
科研与开发

CoPC/g-C3N4的制备及其光催化降解苯酚性能研究

    贾建岗, 何淑媛
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Preparation of CoPC/g-C3N4 and study on its performance in photocatalytic degradation of phenol

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摘要

采用水热法制备CoPC/g-C3N4复合催化剂,并研究其光催化降解苯酚的性能。通过FT-IR、SEM、XRD、ICP、XPS以及电化学测试技术分析催化剂结构和性能关系,提出可能的光催化反应机理。结果表明,相比于单一g-C3N4,CoPC的负载使复合催化剂CoPC/g-C3N4的光催化降解性能提升了1.7倍,CoPC/g-C3N4的苯酚降解率达到82%。光催化性能的提升归因于CoPC的负载提升了CoPC/g-C3N4复合催化剂的光吸收性能,CoPC的负载可以有效增强光生载流子迁移速率,从而提升了光催化降解苯酚的性能。

Abstract

CoPC/g-C3N4 composite catalyst is prepared via a hydrothermal method,and its photocatalytic performance for phenol degradation is studied.The relationship between structure and properties of the catalyst is analyzed by means of FT-IR,SEM,XRD,ICP,XPS and electrochemical testing techniques,and the possible photocatalytic reaction mechanism is proposed.Experimental results show that the photocatalytic degradation performance of CoPC/g-C3N4 increases by 1.7 times than that of single g-C3N4,and the degradation rate of phenol reaches 82% over CoPC/g-C3N4.Characterization results show that the improvement of photocatalytic performance is attributed to the improvement of photo-absorption performance of CoPC/g-C3N4 under CoPC loading.The loading of CoPC can effectively enhance the migration rate of photogenerated carriers,thereby improving the catalyst's performance in photocatalytic degradation of phenol.

关键词

g-C3N4 / 降解 / 苯酚 / 光催化 / 酞菁钴

Key words

g-C3N4 / degradation / phenol / photocatalysis / cobalt phthalocyanine

Author summay

贾建岗(1982-),男,本科,工程师,研究方向为水处理技术,通讯联系人,1210344834@qq.com。

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CoPC/g-C3N4的制备及其光催化降解苯酚性能研究[J]. 现代化工, 2024, 44(10): 180-185 DOI:10.16606/j.cnki.issn0253-4320.2024.10.033

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