PDF (1372K)
摘要
深入剖析了可控/精确自由基聚合技术(CPR)中的3种主要技术:可逆加成-破碎链转移聚合(RAFT)、原子转移自由基聚合(ATRP)和氮氧调控聚合(NMP)。概述了这些技术的基本概念,分析了各个技术方法的优缺点,列举了这些技术方法的应用领域。最后,对可控/精确聚合技术进行了总结和展望。
Abstract
Three primary controlled/precise free radical polymerization (CPR) technologies are analyzed in depth,including Reversible Addition-Fragmentation Chain Transfer (RAFT) Polymerization,Atom Transfer Radical Polymerization (ATRP),and Nitroxide-Mediated Polymerization (NMP).The fundamental concepts of these technologies are outlined,the strength and weakness of each technology are reviewed,and their application domains are listed.A summary and an outlook on controlled/precise polymerization technologies are presented.
关键词
可控反应
/
NMP
/
ATRP
/
RAFT
/
聚合物
/
分子质量控制
Key words
controlled reaction
/
NMP
/
ATRP
/
RAFT
/
polymers
/
molecular weight control
Author summay
唐亮东(1966-),男,硕士,副研究员,研究方向为化学工程与技术、高分子合成材料,nntld@163.com
可控/精确自由基聚合技术的研究及应用进展[J].
, 2024, 44(6): 70-74,78 DOI:10.16606/j.cnki.issn0253-4320.2024.06.015
