碳五回炼对甲醇制烯烃(MTO)反应性能的影响研究

王志军

现代化工 ›› 2024, Vol. 44 ›› Issue (2) : 240 -245.

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现代化工 ›› 2024, Vol. 44 ›› Issue (2) : 240-245. DOI: 10.16606/j.cnki.issn0253-4320.2024.02.043
工业技术

碳五回炼对甲醇制烯烃(MTO)反应性能的影响研究

    王志军
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Study on effect of C5 reprocessing on reaction performance of methanol to olefins

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摘要

甲醇制烯烃(MTO)装置副产混合碳五。为提高碳五组分的高值化利用,国能包头MTO装置采用再生催化剂输送管碳五回炼工艺。混合碳五预裂解增产乙烯和丙烯,同时实现对催化剂的预积碳,提高MTO催化剂活性。通过对比碳五回炼前后装置产出组分的差异,分析碳五回炼对MTO反应性能的影响,结果表明,乙烯和丙烯总收率提高1.03%,乙丙比(乙烯和丙烯比值)降低0.011,综合经济效益提高2 512元/h。

Abstract

A methanol to olefin (MTO) plant mainly produces ethylene, propylene and mixed C5 fractions.In order to improve the high-value utilization of C5 fractions, the Baotou MTO plant adopts a C5 fractions reprocessing process in regenerated catalyst delivery pipe.Mixed C5 fractions reprocessing can increase the production of ethylene and propylene, and at the same time realizes pre-carbon deposition on the catalyst to improve its activity.The effect of C5 fractions reprocessing on MTO reaction performance is analyzed through comparing the differences in the production components of the plant before and after reprocessing C5 fractions.It is indicated that total yield of ethylene and propylene increases by 1.03%, the ethylene-to-propylene ratio decreases by 0.011, and comprehensive economic benefits increases by RMB 2 512 per hour.

关键词

甲醇制烯烃 / 丙烯 / 乙烯 / 碳五裂解 / MTO催化剂

Key words

methanol to olefins / propylene / ethylene / C5 cracking / MTO catalyst

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碳五回炼对甲醇制烯烃(MTO)反应性能的影响研究[J]. 现代化工, 2024, 44(2): 240-245 DOI:10.16606/j.cnki.issn0253-4320.2024.02.043

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