碳量子点修饰电极对生物挂膜及硝氮还原特性研究

王丽, 李瑾, 王文雷, 韩煦葳, 王锦

现代化工 ›› 2023, Vol. 43 ›› Issue (12) : 193 -198.

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现代化工 ›› 2023, Vol. 43 ›› Issue (12) : 193-198. DOI: 10.16606/j.cnki.issn0253-4320.2023.12.035
科研与开发

碳量子点修饰电极对生物挂膜及硝氮还原特性研究

    王丽, 李瑾, 王文雷, 韩煦葳, 王锦
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Characteristics of carbon quantum dot-modified electrode for formation of bio-film and reduction of nitrogen in nitrate

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摘要

研究了不同制备条件下的碳量子点(CQDs)修饰碳毡电极对微生物挂膜及硝酸盐氮(NO3--N)催化还原性能的影响。通过扫描电镜(SEM)和电化学测试方法对其进行测试,结果表明,CQDs质量浓度为14.4 g/L、碳化时间为24 h时,风干干燥方法制备的CQDs修饰电极具有较大的比表面积和良好的挂膜能力;循环伏安曲线分析结果表明,NO3-离子还原峰位于-0.785~-0.663 V之间,峰值电位和峰值电流较大,NO3--N的还原性能更强,同时交流阻抗谱也体现了该工况下较小的电荷转移内阻,均为10~18 Ω之间。因此,使用CQDs修饰可以提升MFC生物阴极的挂膜能力及NO3--N的催化还原性能。

Abstract

The effects of carbon quantum dots (CQDs)-modified carbon felt electrodes prepared under different conditions on the microbial film formation performance of the electrodes and their catalytic reduction performance for nitrogen in nitrate (NO3--N) are investigated.It is indicated through scanning electron microscopy (SEM) and electrochemical test methods that the CQDs modified electrode prepared via air-drying method with a CQDs concentration of 14.44 g·L-1 and a carbonization time of 24 h has a large specific surface area and a good film formation ability.Through cyclic voltammetric curve analysis, it is shown that the reduction peak for NO3- ion locates between -0.785 V and -0.663 V, with larger peak potential and current.The electrode exhibits a stronger reduction performance to NO3--N, while the AC impedance spectrum also reflects the smaller internal resistance of charge transfer under this working condition, all in the range of 10-18 Ω.Therefore, the modification with CQDs can enhance the film formation ability of MFC biocathode and its catalytic reduction performance for NO3--N.

关键词

微生物燃料电池 / 电化学性能 / 催化还原 / 碳量子点 / 生物阴极

Key words

microbial fuel cell / electrochemical performance / catalytic reduction / carbon quantum dot / biocathode

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碳量子点修饰电极对生物挂膜及硝氮还原特性研究[J]. 现代化工, 2023, 43(12): 193-198 DOI:10.16606/j.cnki.issn0253-4320.2023.12.035

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