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摘要
研究了不同制备条件下的碳量子点(CQDs)修饰碳毡电极对微生物挂膜及硝酸盐氮(NO3--N)催化还原性能的影响。通过扫描电镜(SEM)和电化学测试方法对其进行测试,结果表明,CQDs质量浓度为14.4 g/L、碳化时间为24 h时,风干干燥方法制备的CQDs修饰电极具有较大的比表面积和良好的挂膜能力;循环伏安曲线分析结果表明,NO3-离子还原峰位于-0.785~-0.663 V之间,峰值电位和峰值电流较大,NO3--N的还原性能更强,同时交流阻抗谱也体现了该工况下较小的电荷转移内阻,均为10~18 Ω之间。因此,使用CQDs修饰可以提升MFC生物阴极的挂膜能力及NO3--N的催化还原性能。
Abstract
The effects of carbon quantum dots (CQDs)-modified carbon felt electrodes prepared under different conditions on the microbial film formation performance of the electrodes and their catalytic reduction performance for nitrogen in nitrate (NO3--N) are investigated.It is indicated through scanning electron microscopy (SEM) and electrochemical test methods that the CQDs modified electrode prepared via air-drying method with a CQDs concentration of 14.44 g·L-1 and a carbonization time of 24 h has a large specific surface area and a good film formation ability.Through cyclic voltammetric curve analysis, it is shown that the reduction peak for NO3- ion locates between -0.785 V and -0.663 V, with larger peak potential and current.The electrode exhibits a stronger reduction performance to NO3--N, while the AC impedance spectrum also reflects the smaller internal resistance of charge transfer under this working condition, all in the range of 10-18 Ω.Therefore, the modification with CQDs can enhance the film formation ability of MFC biocathode and its catalytic reduction performance for NO3--N.
关键词
微生物燃料电池
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电化学性能
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催化还原
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碳量子点
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生物阴极
Key words
microbial fuel cell
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electrochemical performance
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catalytic reduction
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carbon quantum dot
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biocathode
碳量子点修饰电极对生物挂膜及硝氮还原特性研究[J].
现代化工, 2023, 43(12): 193-198 DOI:10.16606/j.cnki.issn0253-4320.2023.12.035