采用浸渍法将施氏矿物（Sch）负载于ZSM-5型分子筛制备Sch/ZSM-5复合催化剂。利用扫描电子显微镜、EDS能谱仪、比表面积分析仪、X-射线衍射仪和傅里叶红外光谱仪等对其矿相结构进行表征，并结合电化学阻抗谱和循环伏安曲线探究了Sch/ZSM-5活化H₂O₂去除水体中菲的有效性。结果表明，经ZSM-5改性后的Sch扩散程度提高、团聚减少、比表面积增大，可为反应提供更多活性位点。Sch/ZSM-5具有更高的电子转移速率，更易发生≡Fe （Ⅲ）和≡Fe （Ⅱ）的氧化还原，因此对菲的去除有更高的催化活性。当溶液初始pH为3.0、Sch/ZSM-5质量浓度为1.0 g/L、H₂O₂质量浓度为150 mg/L、反应时间为3 h时，1 mg/L菲的去除率可达96.13%。循环反应6次后，菲的去除率仍保持在91.24%，证明Sch/ZSM-5具有良好的可重复利用性和稳定性。

Through the impregnation method, Schwertmanneite (Sch) is loaded on Zeolites Socony Mobil-5(ZSM-5) type molecular sieve to prepare Sch/ZSM-5 composite catalyst, which is characterized by mean of scanning electron microscope (SEM), specific surface area analysis (BET), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), energy dispersive spectrometer (EDS).Combining with the test results by cyclic voltammetry (CV) and electrochemical impedance spectrum (EIS), the effectiveness of Sch/ZSM-5 with H₂O₂ in removing phenanthrene from water is investigated.It is shown that the diffusion of ZSM-5 modified-Sch is increased while the agglomeration and specific surface area decrease.The increased specific surface area can provide more active sites for the reaction.Sch/ZSM-5 presents higher electron transfer rate which can make the redox of ≡Fe(Ⅲ) and ≡Fe(Ⅱ) much easier.Therefore, the system has higher catalytic activity for the removal of phenanthrene.The removal rate of phenanthrene (1 mg·L^-1) reaches 96.13% after 3 h of reaction when the initial pH of the solution is 3.0, the concentration of Sch/ZSM-5 is 1.0 g·L^-1, and the concentration of H₂O₂ is 150 mg·L^-1.After it has been used for 6 cycles of reaction, the removal rate of phenanthrene remains at 91.24%, proving that Sch/ZSM-5 has excellent reusability and stability.