KOH改性碳纳米管负载钴活化过硫酸盐降解BPA的机理研究

胡锋平, 龙兰兰, 陈钧杰, 许莉, 许高平

现代化工 ›› 2023, Vol. 43 ›› Issue (9) : 91 -96.

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现代化工 ›› 2023, Vol. 43 ›› Issue (9) : 91-96. DOI: 10.16606/j.cnki.issn0253-4320.2023.09.020
科研与开发

KOH改性碳纳米管负载钴活化过硫酸盐降解BPA的机理研究

    胡锋平, 龙兰兰, 陈钧杰, 许莉, 许高平
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Degradation mechanism of bis-phenol A by KOH-modified carbon nanotubes supported cobalt activated persulfate

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摘要

通过简单的水热法和KOH活化法制备了一种吸附性能和催化性能优良的材料Co-CNTs-KOH,并对其进行表征分析;考察了Co-CNTs-KOH投加量、BPA初始质量浓度、PMS投加量、pH和离子强度等因素对降解BPA效果的影响。结果表明,所制备的催化剂Co-CNTs-KOH为表面粗糙、疏松多孔的不规则形状,具有较高的结晶度和密集分布的介孔结构;在催化剂质量浓度为20 mg/L、BPA初始质量浓度为20 mg/L、PMS浓度为0.5 mmol/L、弱酸条件下,BPA的降解效果最佳,降解率高达93.5%;通过自由基猝灭反应得出结论,SO4-·和OH·自由基是该体系主要的活性氧化物质。

Abstract

Co-CNTs-KOH, a material with good adsorption and catalytic properties, is prepared by simple hydrothermal method and KOH activation method, and characterized and analyzed.The effects of Co-CNTs-KOH dosage, bisphenol A initial concentration, PMS dosage, pH and ionic strength on the degradation effect of bisphenol A are investigated.The results show that the prepared Co-CNTs-KOH has a rough surface, loose and porous irregular shape, high crystallinity and dense mesoporous structure.It is found that the degradation effect of bisphenol A reaches the best with a degradation rate as high as 93.5% when the catalyst dosage is 20 mg·L-1, the initial concentration of bisphenol A is 20 mg·L-1, the concentration of PMS is 0.5 mM, and under weak acid conditions.Through free radical quenching reaction, it is discovered that SO4-· and OH· radicals are the main active oxidizing substances in the system.

关键词

Co-CNTs-KOH / 双酚A / 过硫酸盐 / 活化

Key words

Co-CNTs-KOH / bisphenol A / persulfates / catalysis

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KOH改性碳纳米管负载钴活化过硫酸盐降解BPA的机理研究[J]. , 2023, 43(9): 91-96 DOI:10.16606/j.cnki.issn0253-4320.2023.09.020

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