微气泡-电催化协同氧化降解高浓度垃圾渗滤液的研究

梁正义, 黄华林, 梁斌, 周俊华, 黄柠, 黄慨

现代化工 ›› 2023, Vol. 43 ›› Issue (2) : 155 -162.

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现代化工 ›› 2023, Vol. 43 ›› Issue (2) : 155-162. DOI: 10.16606/j.cnki.issn0253-4320.2023.02.030
科研与开发

微气泡-电催化协同氧化降解高浓度垃圾渗滤液的研究

    梁正义, 黄华林, 梁斌, 周俊华, 黄柠, 黄慨
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Microbubble-electrocatalytic synergistic oxidation degradation of high-concentration landfill leachate

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摘要

利用微气泡-电催化协同氧化技术对高浓度垃圾渗滤液进行降解研究,考察了电流密度、pH、微气泡通气量等工艺条件对处理高浓度垃圾渗滤液的影响,对比研究了单一使用微汽泡、双氧水、电催化及其双组合协同工艺方案去除COD和氨氮的效果,并采用Design Expert 8软件进行响应面优化协同氧化工艺。结果表明,响应面预测的最优工艺条件为:电流密度为 33.3 mA/cm2、通气量为8.5 L/min、渗滤液初始pH 8.5,在该条件下COD和氨氮的去除率分别为75.3%和97.1%,与预测值(COD为75.0%,氨氮去除率为95.4%)基本相符。

Abstract

Microbubble-electrocatalytic synergic oxidation technology is employed to study the degradation of high concentration of landfill leachate.The influences of current density,pH,microbubble ventilation and other technological conditions on the treatment of high concentration of landfill leachate are investigated.The removal effects of COD and ammoniacal nitrogen by microbubble,hydrogen peroxide,electrocatalysis and their double combination synergic process respectively are compared and studied.The synergic co-oxidation process is optimized in response surface by using Design Expert 8 software.The optimal process conditions by response surface prediction are as follows:the current density is 33.3 mA·cm-2,the ventilation is 8.5 L·min-1,and the initial pH of the leachate is 8.5.Under these conditions,the removal rates of COD and ammoniacal nitrogen are 75.3% and 97.1%,respectively,which is basically consistent with the predicted values.

关键词

垃圾渗滤液 / 协同氧化 / 微气泡-电催化 / 氨氮 / COD

Key words

landfill leachate / synergistic oxidation / microbubble-electrocatalysis / ammoniacal nitrogen / COD

Author summay

梁正义(1989-),男,硕士,工程师,从事环保治理与技术开发研究,597997713@qq.com。

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微气泡-电催化协同氧化降解高浓度垃圾渗滤液的研究[J]. 现代化工, 2023, 43(2): 155-162 DOI:10.16606/j.cnki.issn0253-4320.2023.02.030

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