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摘要
采用水热法合成SnO2/Na0.9Mg0.45Ti3.55O8(SnO2/NMTO)异质结,考察了SnO2/Na0.9Mg0.45Ti3.55O8对罗丹明B(RhB)的光催化活性。结果表明,SnO2/Na0.9Mg0.45Ti3.55O8的光催化活性优于NMTO和SnO2,SnO2的质量分数为10.0%时,具有最好的光催化活性;光照时产生的光生电子大部分迁移到界面处,有助于延长光生电子-空穴对的寿命,从而提高其光催化性能。瞬态光电流响应结果证实,光生电子-空穴对得到了有效分离。
Abstract
SnO2/Na0.9Mg0.45Ti3.55O8 (SnO2/NMTO) heterojunction is synthesized through a hydrothermal technique,and its photocatalytic activity for Rhodamine B (RHB) is investigated.The results show that the photocatalytic activity of SnO2/NMTO is better than NMTO as well as SnO2 in terms of the degradation of RhB.SnO2/NMTO has the best photocatalytic activity when it contains 10% of SnO2.Most of the photogenerated electrons generated during illumination migrate to the interface,which is helpful in prolonging the lifetime of photogenerated electron-hole pairs,thus enhancing the photocatalytic performance of SnO2/NMTO.The results from transient photocurrent responses confirm that photogenerated electron-hole pairs are effectively separated.
关键词
水热法
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光催化活性
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电荷分离
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SnO2/NMTO
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异质结
Key words
hydrothermal method
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photocatalytic activity
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charge separation
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SnO2/NMTO
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heterojunction
SnO2/Na0.9Mg0.45Ti3.55O8异质结的制备及其光催化活性的研究[J].
, 2023, 43(2): 98-103 DOI:10.16606/j.cnki.issn0253-4320.2023.02.020