SnO2/Na0.9Mg0.45Ti3.55O8异质结的制备及其光催化活性的研究

王景州, 张喜生, 马紫微, 姚陈忠

现代化工 ›› 2023, Vol. 43 ›› Issue (2) : 98 -103.

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现代化工 ›› 2023, Vol. 43 ›› Issue (2) : 98-103. DOI: 10.16606/j.cnki.issn0253-4320.2023.02.020
科研与开发

SnO2/Na0.9Mg0.45Ti3.55O8异质结的制备及其光催化活性的研究

    王景州, 张喜生, 马紫微, 姚陈忠
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Preparation of SnO2/Na0.9Mg0.45Ti3.55O8 heterojunction and study on its photocatalytic activity

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摘要

采用水热法合成SnO2/Na0.9Mg0.45Ti3.55O8(SnO2/NMTO)异质结,考察了SnO2/Na0.9Mg0.45Ti3.55O8对罗丹明B(RhB)的光催化活性。结果表明,SnO2/Na0.9Mg0.45Ti3.55O8的光催化活性优于NMTO和SnO2,SnO2的质量分数为10.0%时,具有最好的光催化活性;光照时产生的光生电子大部分迁移到界面处,有助于延长光生电子-空穴对的寿命,从而提高其光催化性能。瞬态光电流响应结果证实,光生电子-空穴对得到了有效分离。

Abstract

SnO2/Na0.9Mg0.45Ti3.55O8 (SnO2/NMTO) heterojunction is synthesized through a hydrothermal technique,and its photocatalytic activity for Rhodamine B (RHB) is investigated.The results show that the photocatalytic activity of SnO2/NMTO is better than NMTO as well as SnO2 in terms of the degradation of RhB.SnO2/NMTO has the best photocatalytic activity when it contains 10% of SnO2.Most of the photogenerated electrons generated during illumination migrate to the interface,which is helpful in prolonging the lifetime of photogenerated electron-hole pairs,thus enhancing the photocatalytic performance of SnO2/NMTO.The results from transient photocurrent responses confirm that photogenerated electron-hole pairs are effectively separated.

关键词

水热法 / 光催化活性 / 电荷分离 / SnO2/NMTO / 异质结

Key words

hydrothermal method / photocatalytic activity / charge separation / SnO2/NMTO / heterojunction

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SnO2/Na0.9Mg0.45Ti3.55O8异质结的制备及其光催化活性的研究[J]. , 2023, 43(2): 98-103 DOI:10.16606/j.cnki.issn0253-4320.2023.02.020

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