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摘要
介绍了自修复材料的研究现状,综述了最近几年基于Diels-Alder反应、二硫键、硼酸酯键等可逆共价键以及氢键、金属配位键、π-π堆积等可逆非共价键的本征型自修复材料的设计制备。展望了基于动态键的自修复聚合物的前景和挑战。
Abstract
This paper introduces the research status of self-healing materials, and reviews the design and preparation of intrinsic self-healing materials based on reversible covalent bonds such as Diels-Alder reaction, disulfide bond and borate ester bond, and reversible non-covalent bonds such as hydrogen bond, metal coordination bond and π-π stacking.The prospects and challenges for self-healing polymers based on dynamic bonds are predicted.
关键词
本征型
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聚合物
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非共价键
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共价键
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自修复
Key words
intrinsic type
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polymer
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non-covalent bond
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covalent bond
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self-healing
Author summay
本征型自修复高分子材料研究进展[J].
, 2022, 42(6): 64-68 DOI:10.16606/j.cnki.issn0253-4320.2022.06.014