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摘要
相邻活性位点间的协同作用可以促进催化活性,同时保持源自原子分散性质的高原子利用率,双金属位点催化剂正成为CO2还原反应研究中的新领域。锚定在氮化碳上的原子级分散的Ni/Co双金属活性位点,可作为一种高效的CO2电还原催化剂。该催化剂在-0.6~-1.1 V的宽电势范围内表现出优异的选择性(CO法拉第效率超过90%),并且在连续电解40 h后仍保持94%的初始选择性,显示出卓越的稳定性。
Abstract
The synergy between adjacent active sites can promote catalytic activity while maintaining high atomic utilization sourced from atomic dispersion properties.Bimetallic site catalyst is becoming a new item in studying CO2 electroreduction reaction.The isolated Ni-Co bimetal active sites anchored on carbon nitride can be used as an efficient catalyst for electroreduction of CO2.This catalyst exhibits excellent selectivity in a wide potential range from -0.6 to -1.1 V vs.RHE (CO Faraday efficiency exceeds 90%),and maintains an initial selectivity of 94% after 40 hours of continuous electrolysis,showing significant stability.This work provides a new perspective for advancing universal synthesis strategies to construct heteronuclear diatomic catalysts.
关键词
二氧化碳电还原
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电化学氢泵反应器
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活性位点
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协同作用
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原子级催化剂
Key words
electroreduction of CO2
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electrochemical hydrogen pump reactor
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active site
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synergistic effect
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atomically dispersed catalyst
Author summay
冯曼曼(1996-),女,硕士研究生,研究方向为纳米催化碳材料在电化学中的应用,fxuman@mail.dlut.edun.cn;吴雪梅(1971-),女,博士,教授,主要从事氢能高效开发利用以及燃料电池、储能液流电池、电化学催化等方面的研究,通讯联系人,xuemeiw@dlut.edu.cn。
孤立的Ni/Co双金属位点协同催化CO2电还原[J].
, 2022, 42(3): 92-97 DOI:10.16606/j.cnki.issn0253-4320.2022.03.019