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摘要
为改善氧化锡(SnO2)的光催化性能,扩大其在印染废水处理领域中的应用,采用简单的水热合成法制备了新型磁性可回收氧化锡/磁性纳米洋葱碳(SnO2/MCNOs)复合材料。采用SEM、XRD、XPS、UV-Vis DRS和FT-IR等分析手段对复合材料进行了研究,并用磁滞回线确定了所制备复合材料的顺磁性。选择10 mg/L的罗丹明B(RhB)作为典型的有机污染物来评价上述制备的复合材料的光降解效率。结果表明,SnO2/MCNOs比纯SnO2具有更好的光催化活性。最后,根据物理化学和光催化性能,提出了所制备复合材料对RhB的降解机理。
Abstract
A novel magnetically retrievable SnO2/magnetic carbon nano-onions (SnO2/MCNOs) composite is synthesized via a simple hydrothermal method, aiming to improve the photocatalytic performance of SnO2 and expand its application in the field of printing and dyeing wastewater treatment.The characteristics of the as-prepared materials are explored by scanning electron microscopy (SEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), ultraviolet visible light diffuse reflection (UV-vis DRS) and Fourier transform infrared spectroscopy (FT-IR) techniques, and the paramagnetic nature is determined by hysteresis loops measurements.Rhodamine B with a concentration of 10 mg·L-1 is chosen as typical organic pollutant to evaluate the photodegradation efficiency of the as-prepared composite.The results indicate that SnO2/MCNOs have a superior performance on photocatalytic activity than pure SnO2.A possible mechanism for the materials to degrade rhodamine B is proposed based on the physic-chemical and photocatalytic properties.
关键词
氧化锡
/
罗丹明B
/
降解
/
光催化
/
磁性纳米洋葱碳
Key words
SnO2
/
rhodamine B
/
degradation
/
photocatalytic
/
magnetic carbon nano-onions
Author summay
师倩莹(1996-),女,硕士生,研究方向为光催化材料,756711713@qq.com
氧化锡/磁性纳米洋葱碳复合材料光催化降解罗丹明B的研究[J].
现代化工, 2021, 41(S1): 241-248,255 DOI:10.16606/j.cnki.issn0253-4320.2021.S.049