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摘要
利用浸渍还原法首次合成绿色环保的Ni-B/KIT-6催化剂,并将其用于α-蒎烯加氢反应。结果表明,与其他催化剂相比,镍系催化剂具有成本低、绿色环保的优点,在较为经济的工艺条件下,能使α-蒎烯加氢达到极高的催化活性;顺式蒎烷在催化剂循环8次后选择性依旧保持在97%以上,高于国内外现有研究水平。最后对催化剂结构进行探讨并分析其失活的原因。
Abstract
Cis-pinane which can be produced through the hydrogenation of α-pinene has important research value in the fields of perfumery and medicine.Ni-B/KIT-6, an environmentally friendly catalyst, is synthesized for the first time by the impregnation reduction method, and used in α-pinene hydrogenation reaction.Compared with other catalysts, the catalyst has the advantages of low cost and environmentally friendliness, and can make α-pinene hydrogenation achieve extremely high catalytic activity under more economical process conditions.The selectivity of cis-pinane remains above 97% after the catalyst has been cycled for 8 times, which is higher than current research level.The structure of the catalyst and the reasons of its deactivation are discussed.
关键词
Ni-B/KIT-6
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顺式蒎烷
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α-蒎烯
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催化
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松节油
Key words
Ni-B/KIT-6
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cis-pinane
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α-pinene
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catalysis
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turpentine
Author summay
黄鹏鹏(1995-),男,硕士研究生,研究方向为天然产物深加工,1120058676@qq.com
三维介孔Ni-B/KIT-6催化剂催化α-蒎烯加氢反应研究[J].
, 2021, 41(10): 78-83,90 DOI:10.16606/j.cnki.issn0253-4320.2021.10.017