为降解工业废水中的苯酚及其衍生物，通过与聚乙烯亚胺（PEI）中的氨基络合将铜离子固定在聚甲基丙烯酸甲酯-聚乙烯亚胺（PMMA/PEI）微粒上，并以过氧化氢（H₂O₂）为氧化剂，将其应用于苯酚水溶液（1.0 g/L）的催化湿式过氧化氢氧化（CWPO）中。结果发现，该微粒是苯酚氧化降解的有效催化剂，其催化活性取决于多种反应因素。在反应温度为70℃、催化剂质量浓度为160 mg/L、氧化剂质量浓度为15.2 g/L、初始pH为5.0、反应时间为20 h的最佳反应条件下，苯酚的转化率约为96%，化学需氧量（COD）去除效率可达到90%。

To degrade phenol and its derivatives in industrial wastewater,polymethyl methacrylate/polyethylenimine-Cu²⁺ (PMMA/PEI-Cu²⁺) particles are prepared by immobilizing copper(Ⅱ) ions onto PMMA/PEI micro particles through complexation with amino groups in PEI.Then the as-prepared PMMA/PEI-Cu²⁺ particles are applied in the catalytic wet peroxide oxidation (CWPO) of phenol aqueous solution (1.0 g·L^-1),with hydrogen peroxide as oxidant.It is found that the particles are an effective catalyst for the oxidative degradation of phenol,with catalytic activity depending on a variety of reaction factors.The conversion of phenol and the removal rate of COD can reach 96% and 90%,respectively under the following optimal conditions:reaction temperature remains at 70℃,the mass concentration of catalyst is 160 mg·L^-1,the mass concentration of oxidant is 15.2 g·L^-1,the initial pH is 5.0 and reaction lasts for 20 h.

胡嘉伟(1995-),男,硕士研究生,研究方向为高分子合成,781979913@qq.com