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摘要
针对石墨相氮化碳(g-C3N4)比表面积小、光生载流子复合过快和可见光利用效率低等缺点,系统阐述了g-C3N4的改性和优化方法,包括设计g-C3N4零维、一维、二维结构,金属掺杂、非金属掺杂,目的是增大比表面积、加快光生电子-空穴对的分离、拓宽对可见光的响应范围;同时讨论了相应的改性方法对光催化性能的影响,从而达到增强光催化性能的目的;最后总结了g-C3N4材料目前存在的问题,并对今后的研究重点和方向提出了展望。
Abstract
Graphite carbon nitride (g-C3N4) has shortcomings such as small specific surface area,too fast photo-generated carrier recombination and low visible light utilization efficiency.In view of the shortcomings,the modification and optimization methods for g-C3N4 are systematically explained,including the design of zero-dimensional,one-dimensional,and two-dimensional structures of g-C3N4,metal doping and non-metal doping,which is aimed at increasing specific surface area,accelerating the separation of electron-hole pairs and broadening the response range to visible light.Influences of these modification methods on the photocatalytic performance of g-C3N4 is discussed,so as to achieve the purpose of enhancing photocatalytic performance.Existing problems of g-C3N4 materials are summarized,and future research focus and directions are suggested.
关键词
石墨相氮化碳
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光催化
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聚合物
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改性
Key words
graphite phase carbon nitride
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photocatalysis
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polymer
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modification
Author summay
g-C3N4基光催化剂改性的研究进展[J].
, 2021, 41(3): 42-47 DOI:10.16606/j.cnki.issn0253-4320.2021.03.009