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摘要
针对传统水凝胶的复杂制备方法及样品综合性能不佳等问题,以纳米Fe3O4和聚丙烯酸为原料,利用仿生矿化法制备了磁响应自修复水凝胶。通过SEM、FT-IR、XRD、TG、磁性测量系统、旋转流变仪对所制备水凝胶的形貌结构及性能进行表征。结果表明,制得的水凝胶结构均匀,对磁场响应灵敏,自修复时间短且可反复自修复,水凝胶的磁性能和流变性能可通过调节纳米Fe3O4的添加量来调控。
Abstract
Traditional preparation methods of hydrogel is complicated and the product samples have poor comprehensive performance.Biomimetic mineralization process is used to prepare magnetic response self-healing hydrogel from nano-Fe3O4 and polyacrylic acid.The structure and properties of the prepared hydrogel are characterized by scanning electron microscope,Fourier transform infrared spectroscopy,X-ray diffraction,magnetic property measurement system and rheometer.The results show that the as-prepared hydrogel has a uniform structure,is sensitive to external magnetic fields,and can self-heal repeatedly within a short time about 5 minutes.The magnetic property and rheology of the hydrogel can be regulated by adjusting the adding amount of nano-Fe3O4.
关键词
水凝胶
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自修复水凝胶
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磁响应水凝胶
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聚丙烯酸
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仿生矿化
Key words
hydrogel
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self-healing hydrogel
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magnetic response hydrogel
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polyacrylic acid
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biomimetic mineralization process
Author summay
王光星(1995-),男,硕士研究生,研究方向为仿生矿化法制备有机无机复合材料,gxwang95@mail.ustc.edu.cn
仿生矿化法制备磁响应自修复水凝胶及其性能研究[J].
现代化工, 2020, 40(6): 114-117,122 DOI:10.16606/j.cnki.issn0253-4320.2020.06.024