介质阻挡放电协同Ag改性钙钛矿型催化剂脱硝研究

董冰岩, 张平, 张雨路, 赵旭武, 李琼

现代化工 ›› 2019, Vol. 39 ›› Issue (12) : 84 -88.

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现代化工 ›› 2019, Vol. 39 ›› Issue (12) : 84-88. DOI: 10.16606/j.cnki.issn0253-4320.2019.12.019
科研与开发

介质阻挡放电协同Ag改性钙钛矿型催化剂脱硝研究

    董冰岩, 张平, 张雨路, 赵旭武, 李琼
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Study on denitration by coordination of dielectric barrier discharge and Ag modified perovskite catalyst

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摘要

采用双极性高压介质阻挡放电协同钙钛矿型催化剂对NOx进行处理,研究了介质阻挡放电协同不同焙烧温度下La0.7Sr0.3Ni0.2Mn0.5Fe0.3O3催化剂及A位不同Ag掺杂量的La0.7-xAgxSr0.3Ni0.2Mn0.5Fe0.3O3催化剂在不同反应条件下对去除NOx的影响,并利用XRD、SEM分析各种催化剂性能。结果表明,焙烧温度为650℃的La0.7Sr0.3Ni0.5Mn0.2Fe0.3O3催化剂的效果最佳;A位掺杂Ag对催化剂进行改性,NO转化率和NOx去除率随着Ag质量分数的增大而降低,两者均在添加量为0.1时达到最大,分别为96.62%和85%。

Abstract

NOx is treated by a bipolar high-pressure medium barrier discharge method coordinated with perovskite catalyst.The influences of La0.7Sr0.3Ni0.2Mn0.5Fe0.3O3 calcined at different temperatures and La0.7-xAgxSr0.3Ni0.2Mn0.5Fe0.3O3 with different amount of A-site Ag dopant amount on the removal of NOx under different reaction conditions are studied.XRD and SEM are utilized to analyze the properties of various catalysts.It is found that La0.7Sr0.3Ni0.5Mn0.2Fe0.3O3 catalyst prepared at the calcination temperature of 650℃ has the best performance.When the catalyst modified through A-site doped Ag is used,the conversion rate of NO and the removal rate of NOx both decrease with the increase of Ag addition.Both rates reach the maximum values,96.62% and 85%,respectively when the addition amount of Ag is 0.1.

关键词

钙钛矿 / 催化剂 / 氮氧化物 / 介质阻挡放电

Key words

perovskite / catalyst / nitrogen oxides / dielectric barrier discharge

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介质阻挡放电协同Ag改性钙钛矿型催化剂脱硝研究[J]. , 2019, 39(12): 84-88 DOI:10.16606/j.cnki.issn0253-4320.2019.12.019

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