碳硅负载氧化铌催化果糖制备5-羟甲基糠醛的研究

杨凤丽, 赵芷言, 仝雪

现代化工 ›› 2019, Vol. 39 ›› Issue (10) : 70 -75.

PDF (1551KB)
现代化工 ›› 2019, Vol. 39 ›› Issue (10) : 70-75. DOI: 10.16606/j.cnki.issn0253-4320.2019.10.016
科研与开发

碳硅负载氧化铌催化果糖制备5-羟甲基糠醛的研究

    杨凤丽, 赵芷言, 仝雪
作者信息 +

Conversion of fructose into 5-hydroxymethylfurfural over carbon-silicon supported niobium oxide

Author information +
文章历史 +
PDF (1587K)

摘要

制备了碳硅负载氧化铌催化剂,并对其催化生物质糖转化为5-羟甲基糠醛(HMF)进行研究,对铌负载量、反应时间、反应温度、催化剂质量等影响因素进行考察。结果表明,铌负载量对催化剂酸量和催化活性及HMF选择性均有重要影响:催化剂酸量随铌质量分数增加而增加,果糖转化率也随之增加;HMF选择性随着铌质量分数增加呈现先上升后下降的变化趋势,铌负载量为5%时,HMF收率最大可达82.8%。

Abstract

Nb2O5/C-Si is prepared and its catalytic properties in conversion of biomass sugar to 5-hydroxymethylfurfural (HMF) are studied.The factors such as niobium oxide loading amount,reaction time,temperature and catalyst dosage are investigated.It is found the niobium oxide loading amount has important impact on the acidity amount and catalytic properties of the catalyst,and the selectivity of HMF.With the increase of niobium oxide loading amount,both the acidity amount of catalyst and the conversion rate of fructose increase while the selectivity of HMF increases firstly and decreases then.The highest yield of HMF can reach 82.8% over 5% Nb2O5/P-C-Si catalyst.

关键词

氧化铌 / 碳硅载体 / 5-羟甲基糠醛

Key words

niobium oxide / carbon-silicon supporter / 5-hydroxymethylfurfural

引用本文

引用格式 ▾
碳硅负载氧化铌催化果糖制备5-羟甲基糠醛的研究[J]. , 2019, 39(10): 70-75 DOI:10.16606/j.cnki.issn0253-4320.2019.10.016

登录浏览全文

4963

注册一个新账户 忘记密码

参考文献

AI Summary AI Mindmap
PDF (1551KB)

228

访问

0

被引

导航
相关文章

AI思维导图

/