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摘要
在FTO导电玻璃上采用磁控溅射法和阳极氧化法制备高度透明TiO2纳米管(TNT)阵列薄膜,然后溅射沉积Pt纳米粒子,退火后获得半透明负载Pt的TiO2纳米管阵列薄膜(TNT-Pt)。通过扫描电子显微镜、X射线衍射、X射线光电子能谱对薄膜的微观形貌和组成成分进行表征,证实了TNT-Pt薄膜中Pt纳米粒子的存在。测试结果表明,相对于纯TNT阵列薄膜,TNT-Pt薄膜的光吸收边缘明显发生红移,可见光照射下的光电转换效率提高到35倍。此外,鉴于薄膜的半透明性,TNT-Pt薄膜的正面和反面在可见光照射下均进行了光电流测试,薄膜表现出非对称性光电性能,即反面照射时的光电性能明显优于正面照射。
Abstract
Highly transparent TiO2 nanotubes (TNT) array film is fabricated through the magnetron sputtering and anodization methods on the FTO glass.Then Pt nanoparticles are deposited on the surface of the as-prepared TNT film by sputtering.After annealing,a semi-transparent Pt-loading TiO2 nanotubes array (TNT-Pt) film is attained.Field emission scanning electron microscopy,X-ray diffraction,and X-ray photoelectron spectroscopy are used to characterize the microstructure and composition of the film,which reveals that Pt nanoparticles exist in the TNT-Pt film.Through performance tests,it is found that in comparison with pure TNT array film,the light absorption edge of TNT-Pt film shows significant redshift and the photoelectric conversion efficiency increases to 35 times under visible light irradiation.Moreover,the photocurrent tests are carried out on the front and back sides of TNT-Pt films under visible light irradiation owing to their semitransparency.It is found that the film exhibits asymmetric photoelectric properties,that is,the photoelectric property with back-side illumination is obviously superior to front-side illumination.
关键词
透明TiO2纳米管阵列薄膜
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非对称性光电性能
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负载Pt
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阳极氧化法
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磁控溅射法
Key words
transparent TiO2 nanotubes array film
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asymmetric photoelectric property
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Pt-loading
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anodization
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magnetron sputtering
负载Pt的透明TiO2纳米管薄膜的非对称性光电性能[J].
现代化工, 2019, 39(6): 153-158 DOI:10.16606/j.cnki.issn0253-4320.2019.06.032