利用乙二胺（EDA）对碳酸丙烯酯（PC）的胺解开环反应制备非异氰酸酯聚氨酯（NIPU）单体，通过NIPU的端位羟基（—OH）与丙烯酰氯（AC）发生酯化反应，合成同时具有氨基甲酸酯键（—NHCOO—）和碳碳双键（C=C）的非异氰酸酯聚氨酯丙烯酸酯（NIPUA）单体。将合成的NIPUA单体与丙烯酸丁酯（BA）、丙烯酸（AA）等丙烯酸类化合物在过氧化苯甲酰（BPO）和N，N-二甲基苯胺（DMP）作用下发生加聚反应，制备出一种新型非异氰酸酯聚氨酯丙烯酸酯胶黏剂，并继续固化。利用红外光谱对合成产物的结构进行表征，结果表明，该胶黏剂在一定的条件下能发生C=C双键的加聚固化反应。通过研究单因素对胶黏剂固化性能的影响，获得胶黏剂固化的最佳工艺。

Non-isocyanate polyurethane (NIPU) monomer is firstly prepared through ring-opening reaction between propylene carbonate (PC) and ethylene diamine (EDA).Then NIPUA monomer with urethane bond (-NHCOO-) and C=C double bond both is synthesized by esterification between acryloyl chloride (AC) and end-hydroxyl of NIPU.The structure of products is confirmed by FT-IR and the synthesis process parameters are optimized by single-factor experiments.Addition polymerization is performed between the synthesized NIPUA monomer and butyl acrylate (BA),acrylic acid (AA) in the presence of benzoyl peroxide (BPO) and N,N-dimethylaniline (DMP),and a new urethane acrylate adhesive is prepared.IR spectra shows that this adhesive can be cured under certain conditions.The synthesis and cure process are optimized by single-factor experiments and the optimal conditions are found.