Pt/TiO2催化间甲基苯酚加氢脱氧路径探究

赵翔宇, 李梅

现代化工 ›› 2019, Vol. 39 ›› Issue (3) : 181 -184,186.

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现代化工 ›› 2019, Vol. 39 ›› Issue (3) : 181-184,186. DOI: 10.16606/j.cnki.issn0253-4320.2019.03.040
科研与开发

Pt/TiO2催化间甲基苯酚加氢脱氧路径探究

    赵翔宇, 李梅
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Major reaction pathways for hydrodeoxygenation of m-cresol over Pt/TiO2 catalyst

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摘要

通过等体积浸渍法制备了催化剂Pt/TiO2。利用间甲基苯酚及其中间产物(甲基环己酮、甲基环己醇、甲基环己烷和甲苯等)在催化剂Pt/TiO2上的反应探究了甲基苯酚加氢脱氧的反应路径。利用XRD、H2-TPR、TEM、NH3-TPD、XPS等对催化剂的表面性质和结构性质进行了表征。结果表明,金属Pt能高度分散在载体TiO2上。Pt/TiO2催化间甲基苯酚加氢脱氧反应主要存在2种路径:一种是间甲基苯酚直接脱氧生成甲苯(DDO路径);另一种是间甲基苯酚先加氢生成甲基环己酮、甲基环己醇,然后脱水生成甲基环己烯,再加氢生成甲基环己烷。

Abstract

Pt/TiO2 catalyst is prepared by incipient wetness impregnation.In order to get the reaction pathways of m-cresol hydrodeoxygenation,m-cresol and its intermediate products such as methyl cyclohexanone,methyl cyclohexanol,methyl cyclohexane and toluene are investigated over Pt/TiO2 catalyst at 250oC and ambient hydrogen pressure.The structures and properties of Pt/TiO2 is also investigated by various techniques such as XRD,TEM,BET,XPS,CO chemisorption,NH3-TPD,H2-TPR etc.It is found that Pt particles disperse highly onto the TiO2 supporter.There are two main reaction pathways for hydrodeoxygenation of m-cresol.The first one is the direct deoxygenation to toluene (DDO path) and the second one is that hydrodeoxygenation of m-cresol forms firstly methylcyclohexanone and methylcyclohexanol over Pt,then these two intermediates perform rapidly dehydration to gain methylcyclohexene that is again hydrogenated to methylcyclohexane.Among these two pathways,DDO path is predominant.

关键词

间甲基苯酚 / 等体积浸渍法 / 反应路径 / 加氢脱氧 / Pt/TiO2

Key words

m-cresol / incipient wetness impregnation / reaction pathways / hydrodeoxygenation / Pt/TiO2

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Pt/TiO2催化间甲基苯酚加氢脱氧路径探究[J]. 现代化工, 2019, 39(3): 181-184,186 DOI:10.16606/j.cnki.issn0253-4320.2019.03.040

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